I am thinking that maybe the problem is not with the calibration. It might be that the buffered solution is already expired since at this point the solution is already not stable and will give a different pH reading than what is expected.
Explanation:
What characteristics must the movement of a person have so that the value of the displacement is equal to the distance traveled?
Displacement is equal to the shortest path covered by an object. It is given by the difference of final position and the initial position.
Distance is equal to the total path covered by an object during the journey.
When an object moves in a straight line path, in this case, the displacement is equal to the distance traveled.
If the solution is treated as an ideal solution, the extent of freezing
point depression depends only on the solute concentration that can be
estimated by a simple linear relationship with the cryoscopic constant:
ΔTF = KF · m · i
ΔTF, the freezing point depression, is defined as TF (pure solvent) - TF
(solution).
KF, the cryoscopic constant, which is dependent on the properties of the
solvent, not the solute. Note: When conducting experiments, a higher KF
value makes it easier to observe larger drops in the freezing point.
For water, KF = 1.853 K·kg/mol.[1]
m is the molality (mol solute per kg of solvent)
i is the van 't Hoff factor (number of solute particles per mol, e.g. i =
2 for NaCl).
