By Gay Lussacs law you can find the pressure. First both temperatures of Celsius must change to Kelvin by adding 273. Temperature one will be 308K and temperature 2 will be 258K
With this info, you can now find the pressure with Lussacs law
P1 = P2
— —
T1 T2
Pressure 1 is given which is 32 psi so just plug it all in and find P2
32 = x
—— ——
308 258
308x = 8256 (Cross multiply)
X = 26.8 (divide both sides by 308)
Answer is 26.8 PSI
This makes sense because as temperature increases pressure increases, as well as when temperature decreases, pressure decreases. Since it’s a colder day the pressure will be lower.
3.47 x
atoms of gold have mass of 113.44 grams.
Explanation:
Data given:
number of atoms of gold = 3.47 x
mass of the gold in given number of atoms = ?
atomic mass of gold =196.96 grams/mole
Avagadro's number = 6.022 X 
from the relation,
1 mole of element contains 6.022 x
atoms.
so no of moles of gold given = 
0.57 moles of gold.
from the relation:
number of moles = 
rearranging the equation,
mass = number of moles x atomic mass
mass = 0.57 x 196.96
mass = 113.44 grams
thus, 3.47 x
atoms of gold have mass of 113.44 grams