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yulyashka [42]
3 years ago
10

The standard Gibbs energy of reaction, ÄG°, for the dissociation of phenol is 56.4 kJ mol-1 at 298 K. Calculate the pKa of pheno

l.
a.
9.88
c.
4.12
b.
22.8
d.
5.24​
Chemistry
1 answer:
Neporo4naja [7]3 years ago
4 0

Answer:

a.

9.88

Explanation:

ΔG = - 2.303 RT log Ka

ΔG is change in free energy at temperature T , Ka is equilibrium constant

- 56.4 x 10³ = 2.303 x 8.31 x 298 logKa

- log Ka = 9.88 .

pKa = 9.88 .

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Consider the following reaction.
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Answer:

162 g Fe₂O₃

Explanation:

To find the mass of Fe₂O₃, you need to (1) convert grams C to moles C (via molar mass from periodic table), then (2) convert moles C to moles Fe₂O₃ (via mole-to-mole ratio from reaction coefficients), and then (3) convert moles Fe₂O₃ to grams (via molar mass). It is important to arrange the ratios/conversions in a way that allows for the cancellation of units. The final answer should have 3 sig figs to reflect the given value.

Molar Mass (C): 12.011 g/mol

2 Fe₂O₃(s) + 3 C(s) ---> 4 Fe(s) + 3 CO₂(g)

Molar Mass (Fe₂O₃): 2(55.845 g/mol) + 3(15.998 g/mol)

Molar Mass (Fe₂O₃): 159.684 g/mol

18.3 g C           1 mole            2 moles Fe₂O₃          159.684 g
--------------  x  ----------------  x  -------------------------  x  -----------------  = 162 g Fe₂O₃
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5 0
1 year ago
1.86 g H2 is allowed to react with 9.75 g N2 , producing 2.87g NH3.
svet-max [94.6K]

Answer:

                     (a)  Theoretical Yield  =  10.50 g

                      (b)   %age yield  = 27.33 %

Explanation:

Answer-Part-(a)

                 The balance chemical equation for the synthesis of Ammonia is as follow;

                                          N₂ + 3 H₂ → 2 NH₃

Step 1: Calculating moles of N₂ as;

                   Moles = Mass / M/Mass

                   Moles = 9.75 g / 28.01 g/mol

                   Moles = 0.348 moles of N₂

Step 2: Calculating moles of H₂ as;

                   Moles = Mass / M/Mass

                   Moles = 1.86 g / 2.01 g/mol

                   Moles = 0.925 moles

Step 3: Finding Limiting reagent as;

According to equation,

                1 mole of N₂ reacts with  =  3 moles of H₂

So,

             0.348 moles of N₂ will react with  =  X moles of H₂

Solving for X,

                     X = 3 mol × 0.348 mol / 1 mol

                     X = 1.044 mol of H₂

It shows that to consume 0.348 moles of N₂ completely we require 1.044 mol of Hydrogen while, as given in statement we are only provided with 0.925 moles of H₂ hence, hydrogen  is limiting reagent. Therefore, H₂ will control the final yield.

Step 4: Calculating moles of Ammonia as,

According to equation,

                3 mole of H₂ produces  =  2 moles of NH₃

So,

             0.925 moles of H₂ will produce  =  X moles of NH₃

Solving for X,

                     X = 2 mol × 0.925 mol / 3 mol

                     X = 0.616 mol of NH₃

Step 5: Calculating theoretical yield of Ammonia as,

                     Theoretical Yield  =  Moles × M.Mass

                     Theoretical Yield  =  0.616 mol  × 17.03 g/mol

                     Theoretical Yield  =  10.50 g

Answer-Part-(b)

                    %age yield  = Actual Yield / Theoretical Yield × 100

                    %age yield  = 2.87 g / 10.50 g × 100

                    %age yield  = 27.33 %

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