Answer:
ΔHr = -103,4 kcal/mol
Explanation:
<u>Using:</u>
<u>AH° (kcal/mol)
</u>
<u>Metano (CH)
</u>
<u>-17,9
</u>
<u>Cloro (CI)
</u>
<u>tetraclorometano (CCI)
</u>
<u>- 33,3
</u>
<u>Acido cloridrico (HCI)
</u>
<u>-22</u>
It is possible to obtain the ΔH of a reaction from ΔH's of formation for each compound, thus:
ΔHr = (ΔH products - ΔH reactants)
For the reaction:
CH₄(g) + Cl₂(g) → CCl₄(g) + HCl(g)
The balanced reaction is:
CH₄(g) + 4Cl₂(g) → CCl₄(g) + 4HCl(g)
The ΔH's of formation for these compounds are:
ΔH CH₄(g): -17,9 kcal/mol
ΔH Cl₂(g): 0 kcal/mol
ΔH CCl₄(g): -33,3 kcal/mol
ΔH HCl(g): -22 kcal/mol
The ΔHr is:
-33,3 kcal/mol × 1 mol + -22 kcal/mol× 4 mol - (-17,9 kcal/mol × 1 mol + 0kcal/mol × 4mol)
<em>ΔHr = -103,4 kcal/mol</em>
<em></em>
I hope it helps!
Answer: 48800g
Explanation:
Using the mathematical relation : Moles = Mass / Molar Mass
Moles = 488
Molar mass of CaCO3 = 40 + 12 + (16 x 3) = 100g/mol
Therefore
488 = mass / 100 = 48800g
Answer:
(a) 7.11x10⁻⁴ M/s
(b) 2.56 mol.L⁻¹.h⁻¹
Explanation:
(a) The reaction is:
O₃(g) + NO(g) → O₂(g) + NO₂(g) (1)
The reaction rate of equation (1) is given by:
(2)
<u>We have:</u>
k: is the rate constant of reaction = 3.91x10⁶ M⁻¹.s⁻¹
[O₃]₀ = 2.35x10⁻⁶ M
[NO]₀ = 7.74x10⁻⁵ M
Hence, to find the inital reacion rate we will use equation (2):
Therefore, the inital reaction rate is 7.11x10⁻⁴ M/s
(b) The number of moles of NO₂(g) produced per hour per liter of air is:
t = 1 h
V = 1 L
![\frac{\Delta[NO_{2}]}{\Delta t} = rate](https://tex.z-dn.net/?f=%5Cfrac%7B%5CDelta%5BNO_%7B2%7D%5D%7D%7B%5CDelta%20t%7D%20%3D%20rate)
![\frac{\Delta[NO_{2}]}{\Delta t} = 7.11 \cdot 10^{-4} M/s*\frac{3600 s}{1 h} = 2.56 mol.L^{-1}.h{-1}](https://tex.z-dn.net/?f=%5Cfrac%7B%5CDelta%5BNO_%7B2%7D%5D%7D%7B%5CDelta%20t%7D%20%3D%207.11%20%5Ccdot%2010%5E%7B-4%7D%20M%2Fs%2A%5Cfrac%7B3600%20s%7D%7B1%20h%7D%20%3D%202.56%20mol.L%5E%7B-1%7D.h%7B-1%7D)
Hence, the number of moles of NO₂(g) produced per hour per liter of air is 2.56 mol.L⁻¹.h⁻¹
I hope it helps you!