Answer:
Pressure = 1.14 atm
Explanation:
Hello,
This question requires us to calculate the final pressure of the bottle after thermal equilibrium.
This is a direct application of pressure law which states that in a fixed mass of gas, the pressure of a given gas is directly proportional to its temperature, provided that volume remains constant.
Mathematically, what this implies is
P = kT k = P / T
P1 / T1 = P2 / T2 = P3 / T3 =........= Pn / Tn
P1 / T1 = P2 / T2
P1 = 1.0atm
T1 = -15°C = (-15 + 273.15)K = 258.15K
P2 = ?
T2 = 21.5°C = (21.5 + 273.15)K = 294.65K
P1 / T1 = P2 / T2
P2 = (P1 × T2) / T1
P2 = (1.0 × 294.65) / 258.15
P2 = 1.14atm
The pressure of the gas after attaining equilibrium is 1.14atm
Answer : The half life of 28-Mg in hours is, 6.94
Explanation :
First we have to calculate the rate constant.
Expression for rate law for first order kinetics is given by:

where,
k = rate constant
t = time passed by the sample = 48.0 hr
a = initial amount of the reactant disintegrate = 53500
a - x = amount left after decay process disintegrate = 53500 - 10980 = 42520
Now put all the given values in above equation, we get


Now we have to calculate the half-life.



Therefore, the half life of 28-Mg in hours is, 6.94