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shepuryov [24]
3 years ago
8

A solution is prepared by adding 100 mL of 1.0 M HC2H3O2 (aq) to 100 mL of 1.0 M NaC2H3O2 (aq). The solution is stirred and its

pH is measured to be 4.73. After 3 drops of 1.0 M HCl are added to the solution, the pH of the solution is measured and is still 4.73. Which of the following equations represents the chemical reaction that accounts for the fact that acid was added but there was no detectable change in pH?(A) H3O+(aq) + OH−(aq) -> 2 H2O(l)
(B) H3O+(aq) + Cl−(aq) -> HCl(g) + H2O(l)
(C) H3O+(aq) + C2H3O2−(aq) -> HC2H3O2(aq) + H2O(l)
(D) H3O+(aq) + HC2H3O2(aq) -> H2C2H3O+(aq) + H2O(l)
Chemistry
1 answer:
DIA [1.3K]3 years ago
5 0

Answer:

(C) H3O+(aq) + C2H3O2−(aq) -> HC2H3O2(aq) + H2O(l)

Explanation:

A buffer is a solution of a weak acid and its salt. It mitigates against changes in acidity or alkalinity of a system. A buffer maintains the pH at a constant value by switching the equilibrium concentration of the conjugate acid or conjugate base respectively.

Addition if an acid shifts the equilibrium position towards the conjugate acid side while addition of a base shifts the equilibrium position towards the conjugate base side.

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An iron chloride compound contains 55.85 grams of iron and 106.5 grams of chlorine. What is the most likely empirical formula fo
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The following data were collected for the rate of disappearance of NO in the reaction 2NO(g)+O2(g)→2NO2(g)::
Anit [1.1K]

Answer:

a) The rate law is: v = k[NO]² [O₂]

b) The units are: M⁻² s⁻¹

c) The average value of the constant is: 7.11 x 10³ M⁻² s⁻¹

d) The rate of disappearance of NO is 0.8 M/s

e) The rate of disappearance of O₂ is 0.4 M/s

Explanation:

The experimental rates obtained can be expressed as follows:

v1 = k ([NO]₁)ᵃ ([O₂]₁)ᵇ = 1.41 x 10⁻² M/s

v2 = k ([NO]₂)ᵃ ([O₂]₂)ᵇ = 5.64 x 10⁻² M/s

v3 = k ([NO]₃)ᵃ ([O₂]₃)ᵇ = 1.13 x 10⁻¹ M/s

where:

k = rate constant

[NO]₁ = concentration of NO in experiment 1

[NO]₂ = concentration of NO in experiment 2

[NO]₃ = concentration of NO in experiment 3

[O₂]₁ = concentration of O₂ in experiment 1

[O₂]₂ = concentration of O₂ in experiment 2

[O₂]₃ = concentration of O₂ in experiment 3

a and b = order of the reaction for each reactive respectively.

We can see these equivalences:

[NO]₂ = 2[NO]₁

[O₂]₂ = [O₂]₁

[NO]₃ = [NO]₂

[O₂]₃ = 2[O₂]₂

So, v2 can be written in terms of the concentrations used in experiment 1 replacing [NO]₂ for 2[NO]₁ and [O₂]₂ by [O₂]₁ :

v2 = k (2 [NO]₁)ᵃ ([O₂]₁)ᵇ

If we rationalize v2/v1, we will have:

v2/v1 = k *2ᵃ * ([NO]₁)ᵃ * ([O₂]₁)ᵇ / k * ([NO]₁)ᵃ * ([O₂]₁)ᵇ (the exponent "a" has been distributed)

v2/v1 = 2ᵃ

ln(v2/v1) = a ln2

ln(v2/v1) / ln 2 = a

a = 2

(Please review the logarithmic properties if neccesary)

In the same way, we can find b using the data from experiment 2 and 3 and writting v3 in terms of the concentrations used in experiment 2:

v3/v2 = k ([NO]₂)² * 2ᵇ * ([O₂]₁)ᵇ / k * ([NO]₂)² * ([O₂]₂)ᵇ

v3/v2 = 2ᵇ

ln(v3/v2) = b ln 2

ln(v3/v2) / ln 2 = b

b = 1

Then, the rate law for the reaction is:

<u>v = k[NO]² [O₂]</u>

Since the unit of v is M/s and the product of the concentrations will give a unit of M³, the units of k are:

M/s = k * M³

M/s * M⁻³ = k

<u>M⁻² s⁻¹ = k </u>

To obtain the value of k, we can solve this equation for every experiment:

k = v / [NO]² [O₂]

for experiment 1:

k = 1.41 x 10⁻² M/s / (0.0126 M)² * 0.0125 M = 7.11 x 10³ M⁻² s⁻¹

for experiment 2:

k = 7.11 x 10³ M⁻² s⁻¹

for experiment 3:

k = 7.12 x 10³ M⁻² s⁻¹

The average value of k is then:

(7.11 + 7.11 + 7.12) x 10³ M⁻² s⁻¹ / 3 = <u>7.11 x 10³ M⁻² s⁻¹ </u>

The rate of the reaction when [NO] = 0.0750 M and [O2] =0.0100 M is:

v = k [NO]² [O₂]

The rate of the reaction in terms of the disappearance of NO can be written this way:

v = 1/2(Δ [NO] / Δt) (it is divided by 2 because of the stoichiometric coefficient of NO)

where (Δ [NO] / Δt) is the rate of disappearance of NO.

Then, calculating v with the data provided by the problem:

v = 7.11 x 10³ M⁻² s⁻¹ * (0.0750M)² * 0.0100M = 0.4 M/s

Then, the rate of disappearance of NO will be:

2v = Δ [NO] / Δt = <u>0.8 M/s</u>

The rate of disappearance of O₂ has to be half the rate of disappearance of NO because two moles of NO react with one of O₂. Then Δ [O₂] / Δt = <u>0.4 M/s</u>

With calculations:

v = Δ [O₂] / Δt = 0.4 M/s (since the stoichiometric coefficient is 1, the rate of disappearance of O₂ equals the rate of the reaction).

3 0
3 years ago
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