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UNO [17]
3 years ago
12

Can you answer the following questions with work, please?A) The conversion of glucose-6-phosphate to fructose-6-phosphate is cat

alyzed by an isomerase enzyme. Glucose-6-phosphate was mixed with the enzyme under standard conditions and the reactions was allowed to come to equilibrium. If the keq' is 0.50 what is the Delta G (degree prime) in kJ/mol?B) The conversion of glucose-6-phosphate to fructose-6-phosphate is catalyzed by an isomerase enzyme. Under cellular conditions (37*C), the glucose-6-phosphate is 6.6 uM and the fructose-6-phosphate is 1.3 uM. If the keq' is 0.50 what is the Delta G in kJ/mol? (Use the Delta G (degree prime) from the previous question)
Chemistry
1 answer:
irga5000 [103]3 years ago
3 0

a) dG0= 1.573 kJ/mol

b)  dG = -2.614 kJ/mol

 Explanation:

a)

Write down the values given in the question,

Glucose-6-phosphate was mixed with the enzyme under standard conditions and the reactions was allowed to come to equilibrium the keq is 0.50

To calculate the delta value ,

dG = -RT ln (Keq)

Putting values:

dG0 = -8.314*273*ln(0.5)

dG0= 1.573 kJ/mol

b)

Glucose-6-phosphate is 6.6 uM and the fructose-6-phosphate is 1.3 uM. If the keq' is 0.50.

To calculate the delta value,

dG = dG0 + RT*ln(Q)

Putting values:

dG = 1573 + 8.314*310*ln(1.3/6.6)

Solving we get:

dG = -2.614 kJ/mol

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Identify the arrows that show removal of thermal energy when matter changes state.
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Let's identify first the phases of matter inside each of those beakers. The first beaker on the left has a compact shape and has its own volume. So, that must be solid. The middle beaker has a compact shape but it takes the shape of its container. So, that must be liquid. The third beaker on the right is gas because the molecules are far away from each other.

After identifying each states, let's investigate the energy for phase change. Let's start with the arrows pointing to the right. The first arrow to the right is a phase change from solid to liquid. The intermolecular forces in a solid is the strongest among the three phases of matter. So, you would need an input of energy to break them apart into liquid. The same is true for the phase change from liquid to gas. Therefore, all the arrows pointing to the right require an input of energy.

The reverse arrows pointing to the left needs to release energy. The molecules in the gas state are free such that they can travel from one point to another easily. They have the highest amount of energy. So, if you want the molecules to come closer together, you need to remove the energy to keep them in place. Therefore, the arrows pointing to the right require removal of energy.
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In a given population, which members are most likely to survive and produce offspring?
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Express the following in regular notation:<br> 3.4 x 10-1
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Answer:

hen working with very large or very small numbers, scientists, mathematicians, and engineers often use scientific notation to express those quantities. Scientific notation uses exponential notation. The following are examples of scientific notation.

Light year: number of miles light travels in one year, about 5,880,000,000,000

           Scientific notation is 5.88 x 1012 miles.

hydrogen atom: has a diameter of about 0.00000005 mm

Scientific notation is 5 x 10-8 mm

Computation with very large numbers is made easier with scientific notation.

Learning to Use Scientific Notation

When a number is written in scientific notation, the exponent tells you if the term is a large or a small number. A positive exponent indicates a large number and a negative exponent indicates a small number that is between 0 and 1.

Since it’s so useful, let’s look more closely at the details of scientific notation format.

Scientific Notation

A positive number is written in scientific notation if it is written as a x 10n where the coefficient a has a value such that 1 ≤ a < 10 and n is an integer.

Look at the numbers below. Which of the numbers is written in scientific notation?

Number

Scientific Notation?

Explanation

1.85 x 10-2

yes

1 ≤1.85 < 10

-2 is an integer

no

is not an integer

0.82 x 1014

no

0.82 is not ≥ 1

10 x 103

no

10 is not < 10

Which number below is written in scientific notation?

A) 4.25 x 100.08

B) 0.425 x 107

C) 42.5 x 105

D) 4.25 x 106

Show/Hide Answer

Writing Decimal Notation in Scientific Notation

Now let’s compare some numbers expressed in both scientific notation and standard decimal notation in order to understand how to convert from one form to the other. Take a look at the tables below. Pay close attention to the exponent in the scientific notation and the position of the decimal point in the decimal notation.

Large Numbers

Small Numbers

Decimal Notation

Scientific Notation

Decimal Notation

Scientific Notation

500.0

5 x 102

0.05

5 x 10-2

80,000.0

8 x 104

0.0008

8 x 10-4

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0.00000043

4.3 x 10-7

62,500,000,000.0

6.25 x 1010

0.000000000625

6.25 x 10-10

To write a large number in scientific notation, move the decimal point to the left to obtain a number between 1 and 10. Since moving the decimal point changes the value, you have to multiply the decimal by a power of 10 so that the expression has the same value.

Let’s look at an example.

180,000. =      18,000.0  x  101

                                                             1,800.00  x 102

                                                                180.000 x 103

                                                                  18.0000 x 104

                                                                    1.80000 x 105

                                   180,000 = 1.8 x 105

Notice that the decimal point was moved 5 places to the left, and the exponent is 5.

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A) 7 x 109

B) 0.68 x 1010

C) 6.8 x 109

D) 68 x 108

Show/Hide Answer

Advanced Question

Represent 1.00357 x 10-6 in decimal form.

A) 1.00357000000

B) 0.000100357

C) 0.000001357

D) 0.00000100357

Show/Hide Answer

To write a small number (between 0 and 1) in scientific notation, you move the decimal to the right and the exponent will have to be negative.

                             0.00004     =        00.0004   x  10-1

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                                       0.00004     =   4 x 10-5

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