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DIA [1.3K]
3 years ago
9

Use mathematics to prove that the 5.50 grams of salicylic acid (C7H6O3) used in this experiment is equal to 0.04 mol.

Chemistry
1 answer:
g100num [7]3 years ago
7 0

Answer:

Please find the answer to the question below

Explanation:

In chemistry, the following mathematical formula is used to calculate the number of moles contained by a substance:

mole = mass of substance (g)/molar mass of substance (g/mol)

Molar mass of salicylic acid (C7H6O3) = 12(7) + 1(6) + 16(3)

= 84 + 6 + 48

= 138g/mol

Mass = 5.50grams

mole = 5.5/138

mole = 0.039

Approximately, the number of moles of 5.5grams of salicylic acid is 0.04moles. This is in accordance with the mole value (0.04) given in this question.

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The equilibrium constant is  K =0.02867

The equilibrium pressure for oxygen gas is  P_{O_2} =  0.09367\  atm

Explanation:

  From the question we are told that

       The equation of the chemical reaction is

                    M_2 O_3 _{(s)} ----> 2M_{(s)} + \frac{3}{2} O_2_{(g)}

   The Gibbs free energy forM_3 O_4_{(s)} is  \Delta G^o_{1}  = -8.80 \ kJ/mol

  The Gibbs free energy forM{(s)} is  \Delta G^o_{2}  = 0 \ kJ/mol

    The Gibbs free energy forO_2{(s)} is  \Delta G^o_{3}  = 0 \ kJ/mol

The Gibbs free energy of the reaction is mathematically represented as

         \Delta G^o_{re} = \sum \Delta G^o _p - \sum G^o _r

         \Delta G^o_{re} = \sum \Delta G^o _1 - \sum( G^o _2 +G^o _3)

Substituting values

From the balanced equation

         \Delta G^o_{re} =[ (2 * 0) + (\frac{3}{2} * 0 )] - [1 * - 8.80]

        \Delta G^o_{re} = 8.80 kJ/mol =8800J/mol

The Gibbs free energy of the reaction can also be represented mathematically as

           \Delta G^o_{re} = -RTln K

Where R is the gas constant with a value of  R = 8.314 J/mol \cdot K

             T is the temperature with a given value  of  T = 298 K

             K is the equilibrium constant

Now equilibrium constant for a reaction that contain gas is usually expressed in term of the partial pressure of the reactant and products that a gaseous in state

The equilibrium constant for this chemical reaction  is mathematically represented as

                          K_p =[ P_{O_2}]^{\frac{3}{2} }

Where   [ P_{O_2}] is the equilibrium pressure of oxygen

         The p subscript shows that we are obtaining the equilibrium constant using the partial pressure of gas in the reaction

Now equilibrium constant the subject on the  second equation of the Gibbs free energy of the reaction

 

           K = e^{- \frac{\Delta G^o_{re}}{RT} }

Substituting values

           K= e^{\frac{8800}{8.314 * 298} }

            K =0.02867

Now substituting this into the equation above to obtain the equilibrium of oxygen

           0.02867 = [P_{O_2}]^{[\frac{3}{2} ]}

multiplying through by 1 ^{\frac{2}{3} }

        P_{O_2} =  [0.02867]^{\frac{2}{3} }

        P_{O_2} =  0.09367\  atm

       

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