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WINSTONCH [101]
2 years ago
10

QUESTION 6 Consider the following reaction between the diatomic and monatomic forms of iodine: I2 (g) <-> 2I (g) When 0.09

5 M I2 is initially placed in a previously empty container and sealed, the system slowly reaches equilibrium. When equilibrium is reached, it is found that there is an equilibrium concentration of 0.0055 M of the monatomic form of iodine. Calculate the (unitless) equilibrium constant Kc. Round your answer to two sig figs, and express it in scientific notation.
Chemistry
1 answer:
aalyn [17]2 years ago
3 0

Answer: The equilibrium constant is 3.3\times 10^{-4}

Explanation:

Initial concentration of I_2 = 0.095 M  

The given balanced equilibrium reaction is,

                            I_2(g)\rightleftharpoons 2I(g)

Initial conc.          0.095 M       0 M

At eqm. conc.     (0.095-x) M   (2x) M

Given : 2x = 0.0055

x = 0.00275

The expression for equilibrium constant for this reaction will be,

K_c=\frac{[l]^2}{[I_2]}  

Now put all the given values in this expression, we get :

K_c=\frac{(0.0055)^2}{(0.095-0.00275)}

K_c=\frac{(0.0055)^2}{0.09225}=0.00033

Thus the equilibrium constant is 3.3\times 10^{-4}

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Hello,

In this case, given the information, we proceed as follows:

A)

N_2(g)+3H_2(g)\rightleftharpoons 2NH_3(g)

B) For the calculation of Kc, we rate the equilibrium expression:

Kc=\frac{[NH_3]^2}{[N_2][H_2]^3}

Next, since at equilibrium the concentration of ammonia is 0.6 M (0.9 mol in 1.5 dm³ or L), in terms of the reaction extent x, we have:

[NH_3]=0.6M=2*x

x=\frac{0.6M}{2}=0.3M

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[H_2]=\frac{4mol}{1.5L}-3*x=2.67M-0.9M=1.77M

Therefore, the equilibrium constant is:

Kc=\frac{(0.6M)^2}{(0.7M)*(1.77M)^3}\\ \\Kc=0.0933

C) In this case, the equilibrium yield of ammonia is clearly 0.9 mol since is the yielded amount once equilibrium is established.

D) Here, since the reaction is endothermic (positive enthalpy change), one way to increase the yield of ammonia is increasing the temperature since heat is reactant for endothermic reactions. Moreover, since this reaction has less moles at the products, another way to increase the yield is increasing the pressure since when pressure is increased the side with fewer moles is favored.

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