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Oliga [24]
3 years ago
6

The exact mechanism of this reaction is a little complicated, as it involves the copper ions. However, the process involves the

formation of small amounts of bromine in situ. Draw the mechanism of the bromination of 4-tert-butyl phenol with Br2. -g
Chemistry
1 answer:
mylen [45]3 years ago
6 0

Answer:

see picture below

Explanation:

The mechanism is in the following picture.

In the first step, the lone pair of oxygen (from the OH) as it's a strong activating group in the molecule, will go to the ring. This will cause that the double bond of the ring of the ortho position, attacks as nucleophyle to the Br2, causing the breaking of the bond.

In the second step, the bromine ion substract the hydrogen from the ortho position, and then, by resonance, the pair of electrons returns to the oxygen of the phenol.

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The depletion of ozone (O3) in the stratosphere has been a matter of great concern among scientists in recent years. It is belie
Deffense [45]

<u>Answer:</u> Nitric oxide is the limiting reagent. The number of moles of excess reagent left is 0.0039 moles. The amount of nitrogen dioxide produced will be 0.7912 g.

<u>Explanation:</u>

To calculate the number of moles, we use the equation

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}   ....(1)

  • <u>For ozone:</u>

Given mass of ozone = 0.827 g

Molar mass of ozone = 48 g/mol

Putting values in above equation, we get:

\text{Moles of ozone}=\frac{0.827g}{48g/mol}=0.0172mol

  • <u>For nitric oxide:</u>

Given mass of nitric oxide = 0.635 g

Molar mass of nitric oxide = 30.01 g/mol

Putting values in above equation, we get:

\text{Moles of nitric oxide}=\frac{0.635g}{30.01g/mol}=0.0211mol

For the given chemical equation:

O_3+NO\rightarrow O_2+NO_2

By Stoichiometry of the reaction:

1 mole of ozone reacts with 1 mole of nitric oxide.

So, 0.0172 moles of ozone will react with = \frac{1}{1}\times 0.0172=0.0172moles of nitric oxide

As, given amount of nitric oxide is more than the required amount. So, it is considered as an excess reagent.

Thus, ozone is considered as a limiting reagent because it limits the formation of product.

  • Amount of excess reagent (nitric oxide) left = 0.0211 - 0.0172 = 0.0039 moles

By Stoichiometry of the reaction:

1 mole of ozone produces 1 mole of nitrogen dioxide.

So, 0.0172 moles of ozone will react with = \frac{1}{1}\times 0.0172=0.0172moles of nitrogen dioxide

Now, calculating the mass of nitrogen dioxide from equation 1, we get:

Molar mass of nitrogen dioxide = 46 g/mol

Moles of nitrogen dioxide = 0.0172 moles

Putting values in equation 1, we get:

0.0172mol=\frac{\text{Mass of nitrogen dioxide}}{46g/mol}\\\\\text{Mass of nitrogen dioxide}=0.7912g

Hence, nitric oxide is the limiting reagent. The number of moles of excess reagent left is 0.0039 moles. The amount of nitrogen dioxide produced will be 0.7912 g.

8 0
3 years ago
Which general equation shows a Single-displacement reaction?
Stella [2.4K]
Hello! The answer is D

A good note for these is when there are three elements, one being a singular element and another a compound and there’s a single switch, this could show a single-displacement

Have a good day gamer.
6 0
1 year ago
There are two naturally occurring isotopes of boron. 10 B has a mass of 10.0129 u. 11 B has a mass of 11.0093 u. Determine the a
Vanyuwa [196]
<h2>Natural Abundance for 10B is 19.60%</h2>

Explanation:

  • The natural isotopic abundance of 10B is 19.60%.
  • The natural isotopic abundance of 11B is 80.40%.
  • The isotopic masses of boron are 10.0129 u and 11.009 u respectively.

For calculation of abundance of both the isotopes -

Supposing it was 50/50, the average mass would be 10.5, so to increase the mass we need a more percentage of 11.

Determining it as an equation -

10x + 11y= 10.8

x+y=1 (ratio)

10x + 10y = 10

By taking the denominator away from the numerator

we get;

y = 0.8

x + y = 1

∴ x = 0.2

To get percentages  we need to multiply it by 100

So, the calculated abundance is 80% for 11 B and 20% 10  B.

5 0
3 years ago
Looking at the car in the picture above, explain how the electrons act to form this compound that is on the surface of the car,
dmitriy555 [2]

Answer:

The correct answer is "Iron and oxygen act as Fe3+ and O2− ions respectively, forming rust (Fe₂O₃) in the presence of water by the formation of an ionic bond".

Explanation:

Rust is formed when iron reacts with oxygen in the presence of water (either if the iron is submerged or exposed to moisture in the air), forming the chemical compound Fe₂O₃. The presence of water is needed for rust formation because iron and oxygen act as ions when they are exposed to water, particularly Fe3+ and O2− ions respectively. The bond formed between these two elements are ionic bonds, because it is comprised of the reaction between a metal (iron) and a non-metal (oxygen).

5 0
3 years ago
Why is the cell membrane essential for cell homeostasis?
Nadya [2.5K]
Hello,

Here is your answer:

The proper answer to this question is option C "To allow waste to exit the cell"! The cell membrane controls the matieral that goes in and out of the cell!

Your answer is C.

If you need anymore help feel free to ask me!

Hope this helps!
3 0
3 years ago
Read 2 more answers
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