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Oliga [24]
3 years ago
6

The exact mechanism of this reaction is a little complicated, as it involves the copper ions. However, the process involves the

formation of small amounts of bromine in situ. Draw the mechanism of the bromination of 4-tert-butyl phenol with Br2. -g
Chemistry
1 answer:
mylen [45]3 years ago
6 0

Answer:

see picture below

Explanation:

The mechanism is in the following picture.

In the first step, the lone pair of oxygen (from the OH) as it's a strong activating group in the molecule, will go to the ring. This will cause that the double bond of the ring of the ortho position, attacks as nucleophyle to the Br2, causing the breaking of the bond.

In the second step, the bromine ion substract the hydrogen from the ortho position, and then, by resonance, the pair of electrons returns to the oxygen of the phenol.

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If the molar absorptivity constant for the red dye solution is 5.56×104 M-1cm-1, calculate the molarity of the red dye solution
Shtirlitz [24]

Explanation:

a) Using Beer-Lambert's law :

Formula used :

A=\epsilon \times c\times l

where,

A = absorbance of solution = 0.945

c = concentration of solution = ?

l = length of the cell = 1.20 cm

\epsilon = molar absorptivity of this solution =5.56\times 10^4 M^{-1} cm^{-1}

0.945=5.56\times 10^4 M^{-1} cm^{-1}\times 1.20 \times c

c=1.4163\times 10^{-5} M=14.16 \mu M

(1\mu M=10^{-6} M)

14.16 μM is the molarity of the red dye solution at the optimal wavelength 519nm and absorbance value 0.945.

b) c=1.4163\times 10^{-5} mol/L

1 L of solution contains 1.4163\times 10^{-5} moles of red dye.

Mass of 1.4163\times 10^{-5} moles of red dye:

1.4163\times 10^{-5}\times 879.86g/mol=0.01246 g

(w/v)\%=\frac{\text{Mass of solute (g)}}{\text{Volume of solvent (mL)}}\times 100

red(w/v)\%=\frac{0.01246 g}{1000 mL}\times 100=0.001246\%

c) In order to dilute red dye solution by 5 times, we will need to add 1 L of water to solution of given concentration.

Concentration of red dye solution = c=1.4163\times 10^{-5} M

Concentration of red solution after dilution = c'

c=c'\times 5

1.4163\times 10^{-5} M=c'\times 5

c'=2.83\times 10^{-6} M

The final concentration of the diluted solution is 2.83\times 10^{-6} M

8 0
3 years ago
Frequency of Deer at Local Pond
zavuch27 [327]

Answer:

a

Explanation:

got it right in study island xD

4 0
3 years ago
Explain, in terms of charge distribution, why a molecule of carbon tetrachloride is a nonpolar molecule.​
Pie

Answer:

Explanation:

The covalent bond is the chemical bond between atoms where electrons are shared, forming a molecule. Covalent bonds are established between non-metallic elements, such as hydrogen H, oxygen O and chlorine Cl. These elements have many electrons in their outermost level (valence electrons) and have a tendency to gain electrons to acquire the stability of the electronic structure of noble gas.

The covalent bond between two atoms can be polar or nonpolar. If the atoms are equal, the bond will be nonpolar (since no atom attracts electrons more strongly). But, if the atoms are different, the bond will be polarized towards the most electronegative atom, because it will be the atom that attracts the electron pair with more force. Then it will be polar.

It can occur in a molecule that the bonds are polar and the molecule is nonpolar. This occurs because of the geometry of the molecule, which causes them to cancel the different equal polar bonds of the molecule.

In carbon tetrachloride the bonds are polar, but the tetrahedral geometry of the molecule causes all four dipoles to cancel out and the molecule to be apolar.

6 0
3 years ago
Excretion of nitrogenous wastes in the form of uric acid has a _______ energy cost of production than excretion as urea. excreti
igomit [66]
Protein increase into nervous
4 0
3 years ago
Hydrogen gas reacts rapidly with oxygen gas in the presence of a platinum catalyst. which equation correctly represents this rea
I am Lyosha [343]

Answer:

2H₂(g) + O₂(g) → 2H₂O(g), in presence of Pt as a catalyst.

Explanation:

The reaction:

<em>2H₂(g) + O₂(g) → 2H₂O(g), in presence of Pt as a catalyst.</em>

2.0 moles of hydrogen gas react with 1.0 mole of oxygen gas to produce 2.0 moles of water vapor in presence of Pt as a catalyst.

5 0
4 years ago
Read 2 more answers
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