We can use this equation for boiling point elevation:
ΔT(b) = i K(b) M
when Δ T(b) is the increase of boiling point of the solution.
and i is ( vant Hoff factor, the number of particles or ions per mole-clue.
and K(b) is boiling point increase constant for the solution ( and for water it is equal 0.52 C° Kg/mol)
We can assume i (vant Hoff factor ) = 1 as the sucrose is nonelectrolyte (not readily ionize).
So for water: Tb° = 100 c° and Kb = 0.52 c° Kg / mol
By substitute at:
ΔTb = i Kb M
∴ = 1 * 0.52 * 3.60 = 1.8432 C°
and when Tb = Tb° + ΔTb
∴ Tb = 100 + 1.8432 = 101.8432 C°
Answer:The following statements are correct: 1,2 and 6
Explanation:
1.The cyclohexane ring adopts a chair conformation in order to minimize its torsional strain. In chair conformation 4 carbon atoms are in one plane 1 carbon atom is above that plane and the other 1 carbon atom is below that plane .This leads to chair conformation in which the bond angles are very close to the ideal tetrahedral angle of 109.5 degrees. The C-C-C bond angle in chair conformation is 110 degrees which is almost equal to the ideal tetrahedral angle.
2. In cyclohexane molecule as the molecule adopts a chair conformation in order to eliminate the torsional strain which would occur if the cyclohexane ring were to be planar. Torsional strain is basically the inter electronic repulsion between the atoms that do not share a bond. So this strain happens on account of eclipsing atoms. In case of eclipse structure there would be a lot of torsional strain. In case of chair conformation all the C-H bonds happen to be completely staggered in nature to eliminate the torsional strain.
3. The ring strain in case of cycloalkanes are dependent upon the number of CH₂ groups present as that would determine the size of the ring and subsequently its structure ,whether the ring would be 5 , 6 or 7 membered .Cyclohexane is a 6 -membered as there are 6CH₂ groups in it and the existence of chair conformation is only for Cyclohexane or for molecules having 6-membered ring . Any change in number of CH₂groups would lead to a different conformational structure.
4.All the bond angles in cyclohexane ring is approximately 110 degrees which is almost equal to the ideal terahedral bond angle. So the bond angles in cyclohexane are optimal.
5.The C-H bonds in cyclohexane are always staggered and never eclipsed in order to reduce there torsional strain.
6.All the bonds in cyclohexane ring are staggered to eliminate the torsional strain. It is quite evident that the cyclohexane ring is completely stable free of the ring strain.So there are no eclipsing bonds present in cyclohexane.
So the statements which are correct 1,2 and 6
Answer:
11.8.4 Distillation Columns
Distillation columns present a hazard in that they contain large inventories of flammable boiling liquid, usually under pressure. There are a number of situations which may lead to loss of containment of this liquid.
The conditions of operation of the equipment associated with the distillation column, particularly the reboiler and bottoms pump, are severe, so that failure is more probable.
The reduction of hazard in distillation columns by the limitation of inventory has been discussed above. A distillation column has a large input of heat at the reboiler and a large output at the condenser. If cooling at the condenser is lost, the column may suffer overpressure. It is necessary to protect against this by higher pressure design, relief valves, or HIPS. On the other hand, loss of steam at the reboiler can cause underpressure in the column. On columns operating at or near atmospheric pressure, full vacuum design, vacuum breakers, or inert gas injection is needed for protection. Deposition of flammable materials on packing surfaces has led to many fires on opening of distillation column for maintenance.
Another hazard is overpressure due to heat radiation from fire. Again pressure relief devices are required to provide protection.
The protection of distillation columns is one of the topics treated in detail in codes for pressure relief such as APIRP 521. Likewise, it is one of the principal applications of trip systems.
Another quite different hazard in a distillation column is the ingress of water. The rapid expansion of the water as it flashes to steam can create very damaging overpressures.
Answer:
B. Adding more protons to a positively charged body until the number of protons matches the number of electrons.
Explanation:
