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solong [7]
3 years ago
6

The C-O stretching frequency of carbon monoxide changes when the molecule coordinates to a metal centre. Does it increase or dec

rease? Explain
Chemistry
1 answer:
andrey2020 [161]3 years ago
3 0

Answer:

decrease

Explanation

During the co ordinate bond between the Carbonyl and The metal ,

The Carbonyl donates the sigma electrons and through the process of back bonding , it accepts the electrons in its pi star orbitals i.e. , the antibonding orbitals , thereby reduces the bond order and which in turns reduces the bond strength and , there fore ,

The IR stretching frequency for CO reduces .

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When 21.45 g of KNO3 was dissolved in water in a calorimeter, the temperature fell from 25.00°C to 14.14 °C. If the heat capacit
pashok25 [27]

25.9 kJ/mol. (3 sig. fig. as in the heat capacity.)

<h3>Explanation</h3>

The process:

\text{KNO}_3\;(s) \to \text{KNO}_3\;(aq).

How many moles of this process?

Relative atomic mass from a modern periodic table:

  • K: 39.098;
  • N: 14.007;
  • O: 15.999.

Molar mass of \text{KNO}_3:

M(\text{KNO}_3) = 39.098 + 14.007 + 3\times 15.999 = 101.102\;\text{g}\cdot\text{mol}^{-1}.

Number of moles of the process = Number of moles of \text{KNO}_3 dissolved:

\displaystyle n = \frac{m}{M} = \frac{21.45}{101.102} = 0.212162\;\text{mol}.

What's the enthalpy change of this process?

Q = C\cdot \Delta T = 0.505 \times (25.00 - 14.14) = 5.4843\;\text{kJ} for 0.212162\;\text{mol}. By convention, the enthalpy change \Delta H measures the energy change for each mole of a process.

\displaystyle \Delta H = \frac{Q}{n} = \frac{5.4843\text{kJ}}{0.212162\;\text{mol}} = 25.8\;\text{kJ}\cdot\text{mol}^{-1}.

The heat capacity is the least accurate number in these calculation. It comes with three significant figures. As a result, round the final result to three significant figures. However, make sure you keep at least one additional figure to minimize the risk of rounding errors during the calculation.

4 0
3 years ago
Suppose you combine two substances but no chemical reaction occurs. Which of the following best describes the result?
FromTheMoon [43]
What best describes the result is a mixture
7 0
3 years ago
40
kap26 [50]

Answer:

what you've asked so I guess the answer will be 10 days

8 0
2 years ago
A white salt containing an unknown metal has the formula MCl and gives a lilac flame during a flame test. the salt could be
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Answer:

C

Explanation:

KCl - the flame test for Potassium produces a lilac flame

7 0
2 years ago
Toothpaste is an alkali. How could you use the toothpaste to show that red cabbage is an indicator?
Alecsey [184]

Answer:

PUT THE TOOTHPAST ON CABBAGE AND CHECK IT OUT AFTER A DAY

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2 years ago
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