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nirvana33 [79]
2 years ago
12

Need answer quick please

Chemistry
1 answer:
Nikolay [14]2 years ago
6 0
.5336
using avogadro’s law
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Which law was used to determine the relationship between the volume and the number of moles?​
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The Mole-Volume Relationship: Avogadro's Law. A plot of the effect of temperature on the volume of a gas at constant pressure shows that the volume of a gas is directly proportional to the number of moles of that gas. This is stated as Avogadro's law.

Explanation:

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The following data were obtained in a kinetics study of the hypothetical reaction A + B + C → products. [A]0 (M) [B]0 (M) [C]0 (
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Answer:

B. First order, Order with respect to C = 1

Explanation:

The given kinetic data is as follows:

A + B + C → Products

     [A]₀     [B]₀    [C]₀       Initial Rate (10⁻³ M/s)

1.   0.4      0.4     0.2       160

2.  0.2      0.4      0.4       80

3.   0.6     0.1       0.2       15

4.   0.2     0.1       0.2        5

5.   0.2     0.2      0.4       20

The rate of the above reaction is given as:

Rate = k[A]^{x}[B]^{y}[C]^{z}

where x, y and z are the order with respect to A, B and C respectively.

k = rate constant

[A], [B], [C] are the concentrations

In the method of initial rates, the given reaction is run multiple times. The order with respect to a particular reactant is deduced by keeping the concentrations of the remaining reactants constant and measuring the rates. The ratio of the rates from the two runs gives the order relative to that reactant.

Order w.r.t A : Use trials 3 and 4

\frac{Rate3}{Rate4}= [\frac{[A(3)]}{[A(4)]}]^{x}

\frac{15}{5}= [\frac{[0.6]}{[0.2]}]^{x}

3 = 3^{x} \\\\x =1

Order w.r.t B : Use trials 2 and 5

\frac{Rate2}{Rate5}= [\frac{[B(2)]}{[B(5)]}]^{y}

\frac{80}{20}= [\frac{[0.4]}{[0.2]}]^{y}

4 = 2^{y} \\\\y =2

Order w.r.t C : Use trials 1 and 2

\frac{Rate1}{Rate2}= [\frac{[A(1)]}{[A(2)]}]^{x}[\frac{[B(1)]}{[B(2)]}]^{y}[\frac{[C(1)]}{[C(2)]}]^{z}

we know that x = 1 and y = 2, substituting the appropriate values in the above equation gives:

\frac{160}{80}= [\frac{[0.4]}{[0.2]}]^{1}[\frac{[0.4]}{[0.4]}]^{2}[\frac{[0.2]}{[0.4]}]^{z}

1 = (0.5)^{z}

z = 1

Therefore, order w.r.t C = 1

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