I can help you with part 1
<u>Answer:</u> The amount of heat required to warm given amount of water is 470.9 kJ
<u>Explanation:</u>
To calculate the mass of water, we use the equation:
Density of water = 1 g/mL
Volume of water = 1.50 L = 1500 mL (Conversion factor: 1 L = 1000 mL)
Putting values in above equation, we get:
To calculate the heat absorbed by the water, we use the equation:
where,
q = heat absorbed
m = mass of water = 1500 g
c = heat capacity of water = 4.186 J/g°C
= change in temperature = 
Putting values in above equation, we get:
Hence, the amount of heat required to warm given amount of water is 470.9 kJ
<span>Both provide approaches to confirming the result of experimentation. Repetition can be developed by one scientist or team continually achieving the expected result but replication requires an independent person or team shows thay can arrive at the same answer independently</span>
Answer:
K = Ka/Kb
Explanation:
P(s) + (3/2) Cl₂(g) <-------> PCl₃(g) K = ?
P(s) + (5/2) Cl₂(g) <--------> PCl₅(g) Ka
PCl₃(g) + Cl₂(g) <---------> PCl₅(g) Kb
K = [PCl₃]/ ([P] [Cl₂]⁽³'²⁾)
Ka = [PCl₅]/ ([P] [Cl₂]⁽⁵'²⁾)
Kb = [PCl₅]/ ([PCl₃] [Cl₂])
Since [PCl₅] = [PCl₅]
From the Ka equation,
[PCl₅] = Ka ([P] [Cl₂]⁽⁵'²⁾)
From the Kb equation
[PCl₅] = Kb ([PCl₃] [Cl₂])
Equating them
Ka ([P] [Cl₂]⁽⁵'²⁾) = Kb ([PCl₃] [Cl₂])
(Ka/Kb) = ([PCl₃] [Cl₂]) / ([P] [Cl₂]⁽⁵'²⁾)
(Ka/Kb) = [PCl₃] / ([P] [Cl₂]⁽³'²⁾)
Comparing this with the equation for the overall equilibrium constant
K = Ka/Kb
