Sorry but do you have any clearer photos? Or can you leave the question below I’ll gladly help
Answer:
The pressure is 4.939 atm
Explanation:
As we know
PV = nRT
where P is the pressure
V is the volume
n is the total number of moles
R is the gas constant
and T is the temperature
Substituting the given values we get -

The pressure is 4.939 atm
Answer:
Second one
Explanation:
I think it's the second cause there's no energy w/o heat. So it's the second.
Answer:
Empirical formula = S₁Cl₂ = SCl₂
Explanation:
The empirical formula of a compound is the simplest whole number ratio of each type of atom in a compound.
This compound contains 31.1% sulfur and 68.9% chlorine.
That is 100g of the compound contains 31.1 g of sulfur and 68.9 g of chlorine.
Convert the mass of each element to moles using the molar mass from the periodic table.
Moles of Sulfur = 
= 0.9699
Moles of Chlorine= 
= 1.9434
Divide each mole value by the smallest number of moles calculated.
Units of sulfur = 
= 1
Units of Chlorine = 
= 2
Empirical formula = S₁Cl₂ = SCl₂