Answer:
4600s
Explanation:

For a first order reaction the rate of reaction just depends on the concentration of one specie [B] and it’s expressed as:
![-\frac{d[B]}{dt}=k[B] - - - -\frac{d[B]}{[B]}=k*dt](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BB%5D%7D%7Bdt%7D%3Dk%5BB%5D%20-%20-%20-%20%20-%5Cfrac%7Bd%5BB%5D%7D%7B%5BB%5D%7D%3Dk%2Adt)
If we have an ideal gas in an isothermal (T=constant) and isocoric (v=constant) process.
PV=nRT we can say that P = n so we can express the reaction order as a function of the Partial pressure of one component.
![-\frac{d[P(N_{2}O_{5})]}{P(N_{2}O_{5})}=k*dt](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BP%28N_%7B2%7DO_%7B5%7D%29%5D%7D%7BP%28N_%7B2%7DO_%7B5%7D%29%7D%3Dk%2Adt)
Integrating we get:
![\int\limits^p \,-\frac{d[P(N_{2}O_{5})]}{P(N_{2}O_{5})}=\int\limits^ t k*dt](https://tex.z-dn.net/?f=%5Cint%5Climits%5Ep%20%5C%2C-%5Cfrac%7Bd%5BP%28N_%7B2%7DO_%7B5%7D%29%5D%7D%7BP%28N_%7B2%7DO_%7B5%7D%29%7D%3D%5Cint%5Climits%5E%20t%20k%2Adt)
![-(ln[P(N_{2}O_{5})]-ln[P(N_{2}O_{5})_{o})])=k(t_{2}-t_{1})](https://tex.z-dn.net/?f=-%28ln%5BP%28N_%7B2%7DO_%7B5%7D%29%5D-ln%5BP%28N_%7B2%7DO_%7B5%7D%29_%7Bo%7D%29%5D%29%3Dk%28t_%7B2%7D-t_%7B1%7D%29)
Clearing for t2:
![\frac{-(ln[P(N_{2}O_{5})]-ln[P(N_{2}O_{5})_{o})])}{k}+t_{1}=t_{2}](https://tex.z-dn.net/?f=%5Cfrac%7B-%28ln%5BP%28N_%7B2%7DO_%7B5%7D%29%5D-ln%5BP%28N_%7B2%7DO_%7B5%7D%29_%7Bo%7D%29%5D%29%7D%7Bk%7D%2Bt_%7B1%7D%3Dt_%7B2%7D)
![ln[P(N_{2}O_{5})]=ln(650)=6.4769](https://tex.z-dn.net/?f=ln%5BP%28N_%7B2%7DO_%7B5%7D%29%5D%3Dln%28650%29%3D6.4769)
![ln[P(N_{2}O_{5})_{o}]=ln(760)=6.6333](https://tex.z-dn.net/?f=ln%5BP%28N_%7B2%7DO_%7B5%7D%29_%7Bo%7D%5D%3Dln%28760%29%3D6.6333)

Answer:
4.993 ×10⁻¹¹ J
Explanation:
The <em>nuclear binding energy</em> is the energy equivalent to the mass defect.
The <em>mass defect</em> is the difference between the mass of a nucleus and the sum of the masses of its nucleons.
<em>Calculate the mass defect
</em>
16 p = 16 × 1.007 28 u = 16.116 48 u
16 n = 16 × 1.008 67 u = 16.138 72 u
Total mass of nucleons = 32.255 20 u
- Mass of S-32 = <u>31.972 070 u
</u>
Mass defect = 0.283 13 u
Convert the <em>unified atomic mass units to kilograms</em>.
Mass defect


Use Einstein’s equation to <em>convert the mass defect into energy</em>


Answer is: boiling point will be changed by 4°C.
Chemical dissociation of aluminium nitrate in water: Al(NO₃)₃ → Al³⁺(aq) + 3NO⁻(aq).
Change in boiling point: ΔT =i · Kb · b.
Kb - molal boiling point elevation constant of water is 0.512°C/m, this the same for both solution.
b - molality, moles of solute per kilogram of solvent., this is also same for both solution, because ther is same amount of substance.
i - Van't Hoff factor.
Van't Hoff factor for sugar solution is 1, because sugar do not dissociate on ions.
Van't Hoff factor for aluminium nitrate solution is approximately 4, because it dissociates on four ions (one aluminium cation and three nitrate anions). So ΔT is four times bigger.