Answer:
See explanation and image attached
Explanation:
The reaction of 1-bromo-2-tert-butylcyclohexane with potassium tert-butoxide is an elimination reaction that occurs by E2 mechanism.
The E2 reaction proceeds faster when the hydrogens are in an antiperiplanar position at an angle of 180 degrees.
This is only attainable in the trans isomer of 1-bromo-2-tert-butylcyclohexane. Hence trans 1-bromo-2-tert-butylcyclohexane reacts faster with potassium tert-butoxide
1.94 moles
I did 35/18.02 because 18.02 is the molar mass of water
Make a ball of clay and embed small beads throughout it. The plum pudding model.
<u>Answer:</u> The
for HCN (g) in the reaction is 135.1 kJ/mol.
<u>Explanation:</u>
Enthalpy change is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles. The equation used to calculate enthalpy change is of a reaction is:
For the given chemical reaction:

The equation for the enthalpy change of the above reaction is:
![\Delta H_{rxn}=[(2\times \Delta H_f_{(HCN)})+(6\times \Delta H_f_{(H_2O)})]-[(2\times \Delta H_f_{(NH_3)})+(3\times \Delta H_f_{(O_2)})+(2\times \Delta H_f_{(CH_4)})]](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20H_f_%7B%28HCN%29%7D%29%2B%286%5Ctimes%20%5CDelta%20H_f_%7B%28H_2O%29%7D%29%5D-%5B%282%5Ctimes%20%5CDelta%20H_f_%7B%28NH_3%29%7D%29%2B%283%5Ctimes%20%5CDelta%20H_f_%7B%28O_2%29%7D%29%2B%282%5Ctimes%20%5CDelta%20H_f_%7B%28CH_4%29%7D%29%5D)
We are given:

Putting values in above equation, we get:
![-870.8=[(2\times \Delta H_f_{(HCN)})+(6\times (-241.8))]-[(2\times (-80.3))+(3\times (0))+(2\times (-74.6))]\\\\\Delta H_f_{(HCN)}=135.1kJ](https://tex.z-dn.net/?f=-870.8%3D%5B%282%5Ctimes%20%5CDelta%20H_f_%7B%28HCN%29%7D%29%2B%286%5Ctimes%20%28-241.8%29%29%5D-%5B%282%5Ctimes%20%28-80.3%29%29%2B%283%5Ctimes%20%280%29%29%2B%282%5Ctimes%20%28-74.6%29%29%5D%5C%5C%5C%5C%5CDelta%20H_f_%7B%28HCN%29%7D%3D135.1kJ)
Hence, the
for HCN (g) in the reaction is 135.1 kJ/mol.