Answer:
See explaination
Explanation:
The mole balance for a constant-volume batch reactor is given such as, For a first-order isothermal reaction, the time to reach a given conversion is the same for constant-pressure and constant-volume reactors. Also, the time is the same for a reaction of any order if there is no change in the number of moles.
Please kindly check attachment for the step by step solution of the given problem.
Answer:
The fluoride which precipitates first is CaF₂
Explanation:
When F⁻ is added, CaF₂ and BaF₂ are produced following the ksp equation:
For CaF₂:
Ksp = 3.2x10⁻¹¹ = [Ca²⁺] [F⁻]²
<em>Where [Ca²⁺] = 0.075M * {35mL / (25mL + 35mL)} = 0.04375M</em>
3.2x10⁻¹¹ = [0.04375M] [F⁻]²
[F⁻]² = 7.31x10⁻¹⁰
[F⁻] = 2.7x10⁻⁵M
<h3>CaF₂ begins precipitation when [F⁻] = 2.7x10⁻⁵M.</h3>
For BaF₂:
Ksp = 1.5x10⁻⁶ = [Ba²⁺] [F⁻]²
<em>Where [Ba²⁺] = 0.090M * {25mL / (25mL + 35mL)} = 0.0375M</em>
1.5x10⁻⁶ = [0.0375M] [F⁻]²
[F⁻]² = 4x10⁻⁵
[F⁻] = 6.3x10⁻³M
BaF₂ begins precipitation when [F⁻] = 6.3x10⁻³M
Thus, the fluoride which precipitates first is CaF₂
C. They’re safe to use without the regulation of a physician, according to a regulatory agency
N, our atmosphere is about 80% nitrogen(N) and about 20% oxygen(O)
