Solution :
Time (sec) Volume of NaOH (mL)
339 26.23
1242 27.80
2745 29.70
4546 3.81
39.81
Now the example of the first order kinetics w.r.t volumetric analysis is :
Here, 
= volume at time 0 = 0
Since the interval is not constant, we take the time interval as
= 1402.3333
≈ 1402 seconds
= 0.001643 x 0.52045
= 0.00082
Therefore, the first order rate constant is k .
Answer:
See explanation
Explanation:
The reaction to be considered is shown below;
H2CO3<------->CO2 + H2O
We know that when a constraint such as a sudden change in concentration, pressure or temperature is imposed on a reaction system in equilibrium, the system has to adjust itself by shifting in a particular direction in order to cancel the constraint.
Now, if we remove CO2, the equilibrium position must shift to the right by the decomposition of more H2CO3 to establish equilibrium again.
Answer:
Explanation:
Mg + 2HCl = Mg Cl₂ + H₂
.594 g = .594 / 24.3
= .02444 mole
Heat evolved = msΔ T , m is mass of water ( solvant ) , s is specific heat of water , Δ T is rise in temperature
= 100 x 4.2 x ( 41.83 - 25 )
= 7068.6 J
.02444 mole of Mg evolves 7068.6 J of heat
1 mole of Mg evolves 7068.6 /.02444 J
= 289222.6 J
= 289 kJ .
Molar heat enthalpy = 289 kJ .
Answer:
Graphics can sometimes convey more information in a brief amount of space than an author can explain in a paragraph.
Answer:
The new temperature is 373 K
Explanation:
Step 1: Data given
Volume air = 5000 mL = 5.0 L
Temperature = 223K
New volume = 8.36 L
Step 2: Calculate the new temperature
V1/T1 = V2/T2
⇒V1 = the initial volume = 5.0 L
⇒T1 = the initial temperature = 223 K
⇒V2 = the new volume = 8.36 L
⇒T2 = the new temperature
5.0/223 = 8.36 /T2
T2 = 373 K
The new temperature is 373 K
