Answer:
11419 J/g/ 11.419 KJ/g
Explanation:
H=MCQ
H=225×2.03×(-15-10)
H=225×2.03(25) Note; negative sign is of no use
H=11419J/g
Answer:
S = 7.9 × 10⁻⁵ M
S' = 2.6 × 10⁻⁷ M
Explanation:
To calculate the solubility of CuBr in pure water (S) we will use an ICE Chart. We identify 3 stages (Initial-Change-Equilibrium) and complete each row with the concentration or change in concentration. Let's consider the solution of CuBr.
CuBr(s) ⇄ Cu⁺(aq) + Br⁻(aq)
I 0 0
C +S +S
E S S
The solubility product (Ksp) is:
Ksp = 6.27 × 10⁻⁹ = [Cu⁺].[Br⁻] = S²
S = 7.9 × 10⁻⁵ M
<u>Solubility in 0.0120 M CoBr₂ (S')</u>
First, we will consider the ionization of CoBr₂, a strong electrolyte.
CoBr₂(aq) → Co²⁺(aq) + 2 Br⁻(aq)
1 mole of CoBr₂ produces 2 moles of Br⁻. Then, the concentration of Br⁻ will be 2 × 0.0120 M = 0.0240 M.
Then,
CuBr(s) ⇄ Cu⁺(aq) + Br⁻(aq)
I 0 0.0240
C +S' +S'
E S' 0.0240 + S'
Ksp = 6.27 × 10⁻⁹ = [Cu⁺].[Br⁻] = S' . (0.0240 + S')
In the term (0.0240 + S'), S' is very small so we can neglect it to simplify the calculations.
S' = 2.6 × 10⁻⁷ M
<span>D.) Oxygen would acquire a stable arrangement of electrons by bonding with two atoms of "Magnesium"
[ As Mg has 2 extra electrons & their size are quite similar ]
Hope this helps!</span>
Answer:
![[Ag^{+}]=4.2\times 10^{-2}M](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%3D4.2%5Ctimes%2010%5E%7B-2%7DM)
Explanation:
Given:
[AgNO3] = 0.20 M
Ba(NO3)2 = 0.20 M
[K2CrO4] = 0.10 M
Ksp of Ag2CrO4 = 1.1 x 10^-12
Ksp of BaCrO4 = 1.1 x 10^-10
![Ksp=[Ba^{2+}][CrO_{4}^{2-}]](https://tex.z-dn.net/?f=Ksp%3D%5BBa%5E%7B2%2B%7D%5D%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![1.2\times 10^{-10}=(0.20)[CrO_{4}^{2-}]](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-10%7D%3D%280.20%29%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![[CrO_{4}^{2-}]=\frac{1.2\times 10^{-10}}{(0.20)}= 6.0\times 10^{-10}](https://tex.z-dn.net/?f=%5BCrO_%7B4%7D%5E%7B2-%7D%5D%3D%5Cfrac%7B1.2%5Ctimes%2010%5E%7B-10%7D%7D%7B%280.20%29%7D%3D%206.0%5Ctimes%2010%5E%7B-10%7D)
Now,
![Ksp=[Ag^{+}]^{2}[CrO_{4}^{2-}]](https://tex.z-dn.net/?f=Ksp%3D%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![1.1\times 10^{-12}=[Ag^{+}]^{2}](6.0\times 10^{-10})](https://tex.z-dn.net/?f=1.1%5Ctimes%2010%5E%7B-12%7D%3D%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5D%286.0%5Ctimes%2010%5E%7B-10%7D%29)
![[Ag^{+}]^{2}]=\frac{1.1\times 10^{-12}}{(6.0\times 10^{-10})}= 1.8\times 10^{-3}](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5D%3D%5Cfrac%7B1.1%5Ctimes%2010%5E%7B-12%7D%7D%7B%286.0%5Ctimes%2010%5E%7B-10%7D%29%7D%3D%201.8%5Ctimes%2010%5E%7B-3%7D)
![[Ag^{+}]=\sqrt{1.8\times 10^{-3}}=4.2\times 10^{-2}M](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%3D%5Csqrt%7B1.8%5Ctimes%2010%5E%7B-3%7D%7D%3D4.2%5Ctimes%2010%5E%7B-2%7DM)
So, BaCrO4 will start precipitating when [Ag+] is 4.2 x 1.2^-2 M
