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WITCHER [35]
3 years ago
10

How many milliliters of a 3.4 M NaCl solution would be needed to prepare each solution?

Chemistry
1 answer:
Ksenya-84 [330]3 years ago
8 0

Answer:

a. Approximately 1.3\; \rm mL.

b. Approximately 7.2\; \rm mL.

Explanation:

The unit of concentration "\rm M" is equivalent to "\rm mol \cdot L^{-1}", which means "moles per liter."

However, the volume of both solutions were given in mililiters \rm mL. Convert these volumes to liters:

\displaystyle 45\; \rm mL = 45\; \rm mL \times \frac{1\; \rm L}{1000\; \rm mL} = 0.045\; \rm L.

\displaystyle 330\; \rm mL = 330\; \rm mL \times \frac{1\; \rm L}{1000\; \rm mL} = 0.330\; \rm L.

In a solution of volume V where the concentration of a solute is c, there would be c \cdot V (moles of) formula units of this solute.

Calculate the number of moles of \rm NaCl formula units in each of the two solutions:

Solution in a.:

n = c \cdot V = 0.045\; \rm L \times 0.10\; \rm mol \cdot L^{-1} = 0.0045\; \rm mol.

Solution in b.:

n = c \cdot V = 0.330\; \rm L \times 0.074\; \rm mol \cdot L^{-1} = 0.02442\; \rm mol.

What volume of that 3.4\; \rm M (same as 3.4 \; \rm mol \cdot L^{-1}) \rm NaCl solution would contain that many

For the solution in a.:

\displaystyle V = \frac{n}{c} = \frac{0.0045\; \rm mol}{3.4\; \rm mol \cdot L^{-1}} \approx 0.0013\; \rm L.

Convert the unit of that volume to milliliters:

\displaystyle 0.0013\; \rm L = 0.0013\; \rm L \times \frac{1000\; \rm mL}{1\; \rm L} = 1.3\; \rm mL.

Similarly, for the solution in b.:

\displaystyle V = \frac{n}{c} = \frac{0.02442\; \rm mol}{3.4\; \rm mol \cdot L^{-1}} \approx 0.0072\; \rm L.

Convert the unit of that volume to milliliters:

\displaystyle 0.0072\; \rm L = 0.0072\; \rm L \times \frac{1000\; \rm mL}{1\; \rm L} = 7.2\; \rm mL.

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Answer:

11.61 is the pH of 10.0 mL of a solution containing 3.96 g of sodium stearate.

Explanation:

Concentration of sodium stearate acid : c

Moles of sodium stearate = \frac{3.96 g}{306 g/mol}=0.01294 mol

Volume of the solution = 10.0 mL = 0.010 L

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C_{17}H_{35}COONa\rightleftharpoons C_{17}H_{35}COO^-+Na^+

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C_{17}H_{35}COO^-+H_2O\rightleftharpoons C_{17}H_{35}COOH +OH^-

initially c

c           0    0

At equilibrium

(c-x)       x    x

Dissociation constant of an acid = K_a=1.3\times 10^{-5}

Expression of a dissociation constant of an acid is given by:  

K_a=\frac{[C_{17}H_{35}COOH][OH^-]}{[C_{17}H_{35}COO^-]}

K_a=\frac{(x)^2\times x}{(c -x)}

1.3\times 10^{-5}=\frac{x^2}{1.294-x}

Solving for x;

x = 0.0041 M

[OH^-]=0.0041 M

The pOH of the solution:

pOH=-\log[OH^-]=-\log[0.0041 M]=2.39

pH = 14 -pOH

pH = 14 - 2.39 = 11.61

11.61 is the pH of 10.0 mL of a solution containing 3.96 g of sodium stearate.

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