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Answer:
Therefore the equilibrium number of vacancies per unit cubic meter =2.34×10²⁴ vacancies/ mole
Explanation:
The equilibrium number of of vacancies is denoted by
.
It is depends on
- total no. of atomic number(N)
- energy required for vacancy
- Boltzmann's constant (k)= 8.62×10⁻⁵ev K⁻¹
- temperature (T).

To find equilibrium number of of vacancies we have find N.

Here ρ= 8.45 g/cm³ =8.45 ×10⁶m³
= Avogadro Number = 6.023×10²³
= 63.5 g/mole

g/mole
Here
=0.9 ev/atom , T= 1000k
Therefore the equilibrium number of vacancies per unit cubic meter,

=2.34×10²⁴ vacancies/ mole
Answer:
C.) HOCl Ka=3.5x10^-8
Explanation:
In order to a construct a buffer of pH= 7.0 we need to find the pKa values of all the acids given below
we Know that
pKa= -log(Ka)
therefore
A) pKa of HClO2 = -log(1.2 x 10^-2)
=1.9208
B) similarly PKa of HF= -log(7.2 x 1 0^-4)= 2.7644
C) pKa of HOCl= -log(3.5 x 1 0^-8)= 7.45
D) pKa of HCN = -log(4 x 1 0^-10)= 9.3979
If we consider the Henderson- Hasselbalch equation for the calculation of the pH of the buffer solution
The weak acid for making the buffer must have a pKa value near to the desired pH of the weak acid.
So, near to value, pH=7.0. , the only option is HOCl whose pKa value is 7.45.
Hence, HOCl will be chosen for buffer construction.