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Answer : The
for this reaction is, -88780 J/mole.
Solution :
The balanced cell reaction will be,

Here, magnesium (Cu) undergoes oxidation by loss of electrons, thus act as anode. silver (Ag) undergoes reduction by gain of electrons and thus act as cathode.
The half oxidation-reduction reaction will be :
Oxidation : 
Reduction : 
Now we have to calculate the Gibbs free energy.
Formula used :

where,
= Gibbs free energy = ?
n = number of electrons to balance the reaction = 2
F = Faraday constant = 96500 C/mole
= standard e.m.f of cell = 0.46 V
Now put all the given values in this formula, we get the Gibbs free energy.

Therefore, the
for this reaction is, -88780 J/mole.
Answer:
case1.
The addition of acid and base leads to a change in pH of the water when adding to deionized water due to fact that acid and bases dissociated in dissolving in water. If the H+ ion increases in the water as acid addition hikes it, it will result in decreasing the pH value. The intensity of the acid also affects the dissociation of the ions.
case2
Buffers are normally formed by weak acid and its conjugate base, and adding acid to the buffer it absorbs the H+ ions so the pH will be lower and adding base or increase of OH- conjugate base resists the pH value to increase.