Explanation:
Starting moles of ethanol acid = 0.020 mol
At the equilibrium 50 % of the ethanol acid molecules reacted
∴ Moles of ethanol acid reacted = 0.020 mol * 50 %/100 %
= 0.010 mol
Moles of ethanol acid remain = 0.020 mol + 0.010 mol = 0.010 mol
Moles of the product 
gas formed are calculated as
0.010 mol CH3COOH * 1 mol / 2 mol CH3COOH
= 0.005 mol
Therefore at the equilibrium total moles of gas present in the vessel are 0.010 mol CH3COOH and 0.005 mol
That is total gas moles at equilibrium = 0.010 mol + 0.005 mol = 0.015 mol
Now Calculate the pressure :
0.020 mol gas has pressure of 0.74 atm therefore at the same condition what will be the pressure exerted by 0.015 mol gas
P1/n1 = P2/n2
P2 = P1*n2 / n1
= 0.74 atm * 0.015 mol / 0.020 mol
= 0.555 atm
1mol=6.022x10^23 atoms
3.75mol= 6.022x3.75x10^23 atoms
=2.2583x10^24 atoms
Answer:
Mostly Para
Explanation:
First, let's assume that the molecule is the toluene (A benzene with a methyl group as radical).
Now the nitration reaction is a reaction in which the nitric acid in presence of sulfuric acid, react with the benzene molecule, to introduce the nitro group into the molecule. The nitro group is a relative strong deactiviting group and is metha director, so, further reactions that occur will be in the metha position.
Now, in this case, the methyl group is a weak activating group in the molecule of benzene, and is always ortho and para director for the simple fact that this molecule (The methyl group) is a donor of electrons instead of atracting group of electrons. Therefore for these two reasons, when the nitration occurs,it will go to the ortho or para position.
Now which position will prefer to go? it's true it can go either ortho or para, however, let's use the steric hindrance principle. Although the methyl group it's not a very voluminous and big molecule, it still exerts a little steric hindrance, and the nitro group would rather go to a position where no molecule is present so it can attach easily. It's like you have two doors that lead to the same place, but in one door you have a kid in the middle and the other door is free to go, you'll rather pass by the door which is free instead of the door with the kid in the middle even though you can pass for that door too. Same thing happens here. Therefore the correct option will be mostly para.
Distillation is a process of separating the component substances from a liquid mixture by selective evaporation and condensation.
Empirical formula is calculated as follows
calculate the moles of each element, that is % composition/ molar mass
molar masses ( Si= 28.09g/mol , Cl= 35.5 g/mol, I=126.9 g/mol)
moles of silicon = 7.962/28.09g/mol= 0.283 moles
moles of chlorine = 20.10 / 35.5g/mol = 0.566 moles
moles of iodine= 71.94 / 126.9 g/mol= 0.567 moles
divide each mole with smallest mole (0.283)
that is silicon = 0.283/0.283= 1 mole
chlorine = 0.566/0.283= 2 mole
Iodine= o.567/0.283= 2 moles
empirical formula is therefore= SiCl2I2
