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2 years ago

Unknown # 21

Chemistry

1 answer:

Nutka1998 [239]2 years ago

8 0

Answer is option B
Addictive and always Agn02

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A 2.5 mg sample of magnesium powder is ignited with 2 mg oxygen in a sealed container. All of the magnesium is consumed and 4.15

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Total mass of product = 4.15 mg

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. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are

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<u>Answer:</u> The standard free energy change of formation of $S^{2-}(aq.)$ is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

$K_{sp}\text{ of }Ag_2S=8\times 10^{-51}$

Relation between standard Gibbs free energy and equilibrium constant follows:

$\Delta G^o=-RT\ln K$

where,

$\Delta G^o$ = standard Gibbs free energy = ?

R = Gas constant = $8.314J/K mol$

T = temperature = $25^oC=[273+25]K=298K$

K = equilibrium constant or solubility product = $8\times 10^{-51}$

Putting values in above equation, we get:

$\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ$

For the given chemical equation:

$Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)$

The equation used to calculate Gibbs free change is of a reaction is:

$\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]$

The equation for the Gibbs free energy change of the above reaction is:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]$

We are given:

$\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ$

Putting values in above equation, we get:

$285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol$

Hence, the standard free energy change of formation of $S^{2-}(aq.)$ is 92.094 kJ/mol

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