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Natasha2012 [34]
3 years ago
9

Differences between allotropy and isotopy​

Chemistry
1 answer:
raketka [301]3 years ago
3 0

Answer:

Property of an element by virtue of which it exists in two or more forms which differ only in their physical properties is known as allotropy. Allotropes are the different physical forms in which the element can exist. Allotropes are different physical forms of the same element.

Also-

Allotropes are different forms of the same element in the molecular level. Isotopes are different forms of atoms of the same chemical element. The key difference between allotropes and isotopes is that allotropes are considered at the molecular level, whereas isotopes are considered at the atomic leve

Explanation:

~Hope this helps~

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There are 26 electrons in the nickel ion in the compound NiS.

<h3>How many electrons does the nickel ion contain in the compound NiS?</h3>

The number of electrons in a neutral Nickel atom is obtained from the atomic number of Nickel.

The atomic number of Nickel is 28, therefore, the neutral nickel atom has 28 electrons.

In  the compound NiS, nickel atom loses two electrons to to form the nickel ion.

Number of electrons left = 28 - 2 = 26

Therefore, there are 26 electrons in the nickel ion in the compound NiS.

In conclusion, nickel atom loses two electrons to form nickel ion in NiS.

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Consider the following reaction: A(g)⇌2B(g). Find the equilibrium partial pressures of A and B for each of the following differe
Illusion [34]

Answer:

a. Kp=1.4

P_{A}=0.2215 atm

P_{B}=0.556 atm

b.Kp=2.0 * 10^-4

P_{A}=0.495atm

P_{B}=0.00995 atm

c.Kp=2.0 * 10^5

P_{A}=5*10^{-6}atm

P_{B}=0.9999 atm

Explanation:

For the reaction  

A(g)⇌2B(g)

Kp is defined as:

Kp=\frac{(P_{B})^{2}}{P_{A}}

The conditions in the system are:

          A                    B

initial   0                1 atm

equilibrium x       1atm-2x

At the beginning, we don’t have any A in the system, so B starts to react to produce A until the system reaches the equilibrium producing x amount of A. From the stoichiometric relationship in the reaction we get that to produce x amount of A we need to 2x amount of B so in the equilibrium we will have 1 atm – 2x of B, as it is showed in the table.    

Replacing these values in the expression for Kp we get:

Kp=\frac{(1-2x)^{2}}{x}

Working with this equation:

x*Kp=(1-2x)^{2} - -> x*Kp=4x^{2}-4x+1- - >4x^{2}-(4+Kp)*x+1=0

This last expression is quadratic expression with a=4, b=-(4+Kp) and c=1

The general expression to solve these kinds of equations is:

x=\frac{-b(+-)*\sqrt{(b^{2}-4ac)}}{2a} (equation 1)

We just take the positive values from the solution since negative partial pressures don´t make physical sense.

Kp = 1.4

x_{1}=\frac{(1.4+4)+\sqrt{(-(1.4+4)^{2}-4*4*1)}}{2*4}=1.128

x_{1}=\frac{(1.4+4)-\sqrt{(-(1.4+4)^{2}-4*4*1)}}{2*4}=0.2215

With x1 we get a partial pressure of:

P_{A}=1.128 atm

P_{B}=1-2*1.128 = -1.256 atm

Since negative partial pressure don´t make physical sense x1 is not the solution for the system.

With x2 we get:

P_{A}=0.2215 atm

P_{B}=1-2*0.2215 = 0.556 atm

These partial pressures make sense so x2 is the solution for the equation.

We follow the same analysis for the other values of Kp.

Kp=2*10^-4

X1=0.505

X2=0.495

With x1

P_{A}=0.505atm

P_{B}=1-2*0.505 = -0.01005 atm

Not sense.

With x2

P_{A}=0.495atm

P_{B}=1-2*0.495 = 0.00995 atm

X2 is the solution for this equation.  

Kp=2*10^5

X1=50001

X2=5*10^{-6}

With x1

P_{A}=50001atm

P_{B}=1-2*50001=-100001atm

Not sense.

With x2

P_{A}= 5*10^{-6}atm

P_{B}=1-2*5*10^{-6}= 0.9999 atm

X2 is the solution for this equation.  

8 0
3 years ago
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