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grigory [225]
3 years ago
12

What is the oxidation state of S in HSO4^2-? (A.P.E.X)

Chemistry
1 answer:
BlackZzzverrR [31]3 years ago
7 0

I think there is a typo because I've never seen HSO4 2- before in my life. It should be HSO4-. For that, H is 1+ and each Oxygen is 2-0 totaling 8-. So the oxidation state of sulfur +1 - 8 = 7

So the oxidation state of sulfur is +6

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Many double-displacement reactions are enzyme-catalyzed via the "ping pong" mechanism, so called because the reactants appear to
zhenek [66]

Answer:

<u>D. It will decrease by a factor of 4</u>

Explanation:

According to the question , the equation follows :

A+B\rightarrow C+D

Rate law : This states the rate of reaction is directly proportional to concentration of reactants with each reactant raised to some power which may or may not be equal to the stoichiometeric coefficient.

Rate\ \alpha [A]^{a}[B]^{b}

r=[A]^{a}[B]^{b}.................(1)

STEP": First, find out the power "a" and "b"

a+b = 3 (because it is given that the reaction follow 3rd order-kinetics)

According to question, <u><em>doubling the concentration of the first reactant causes the rate to increase by a factor of 2 means,</em></u>

r' = 2r if [A'] = 2[A]

Here [B] is uneffected means [B']=[B]

hence new rate =

r'=[A']^{a}[B']^{b}

Put the value of [A'] , [B'] and r' in the above equation:

2r=[2A]^{a}[B]^{b}...........(2)

Divide equation (1) by (2) we , get

\frac{2r}{r}=\frac{[2A]^{2}[B]^{b}}{[A]^{a}[B]^{b}}

2= 2(\frac{A}{A})^{a}\times (\frac{B}{B})^{b}

Here A and A cancel each other

B and B cancel each other

We get,

2= 2^{a}\times 1^{b}

1^b = 1 ( power of 1 = 1)

2= 2^{a}

This is possible only when a = 1

We know that : a + b = 3

1 + b = 3

b =3 -1  = 2

b = 2

Hence the rate law becomes :

r=[A]^{a}[B]^{b}

<u>r=[A]^{1}[B]^{2}.............(3)</u>

Look in the question now, it is asked to calculate the concentration of [B],if  cut in half

Hence

[B']=1/2[B]

Insert the value of [B'] in equation (3)

r'=[A]^{1}[B']^{2}

r'=[A]^{1}(\frac{1}{2}[B])^{2}

r'=\frac{1}{4}[A]^{1}[B]^{2}............(a)

But

r=[A]^{a}[B]^{b}..............(b)

Compare equation (a) and (b) , we get

new rate r' =

<u>r' = 1/4 r</u>

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Answer:

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Explanation:

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