They don’t, what you even on about
The answer is C. Free Energy.
Activation energy is the energy that must be exceeded before a chemical reaction can occur. Free energy best describes as energy available to do work.
<span>B. S⁰(s) + 2H⁺ + 2e⁻ –--> H2S⁰(g)
by mass: 1 S and 2 H ----> 2 H and 1S True.
by charge : 0 +(2*(+1)) + 2*(-1) = 0, 0+2-2=0, 0 = 0 True.</span>
The masses can be found by substractions:
- Mass of CaSO₄.H2O (hydrate):
16.05 g - 13.56 g = 2.49 g
15.07 g - 13.56 g = 1.51 g
- The mass of water is equal to the difference between the mass of the hydrate and the mass of the anhydrate:
2.49 g - 1.51 g = 0.98 g
- The percent of water is found by the formula:
massWater ÷ massHydrate * 100%
0.98 g ÷ 2.49 g * 100% = 39.36%
- The mole of water is calculated using water's molecular weight (18g/mol):
0.98 g ÷ 18 g/mol = 0.054 mol water
- A similar procedure is made for the mole of salt (CaSO₄ = 136.14 g/mol)
1.51 g ÷ 136.14 g/mol = 0.011 mol CaSO₄
- The ratio of mole of water to mole of anhydrate is:
0.054 mol water / 0.011 mol CaSO₄ = 0.49
In other words the molecular formula for the hydrate salt is CaSO₄·0.5H₂O
To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
