First, recognize that this is an elimination reaction in which hydroxide must leave and a double bond must form in its place. It is likely an E2 reaction. Here is an efficient mechanism:
1) Pre-reaction: Protonate the -OH to make it a good leaving group, water. H2SO4 or any strong H+ donor works. The water is positively charged but still connected to the compound.
2) E2: Use a sterically hindered base, such as tert-butoxide (tButO-) to abstract the hydrogen from the secondary carbon. [You want a sterically hindered base because a strong, non-sterically hindered base could also abstract a hydrogen from one of the two methyl groups on the tertiary carbon, and that leads to unwanted products, which is not efficient]. As the proton of hydrogen is abstracted, water leaves at the same time, creating an intermediate tertiary carbocation, and the 2 electrons in the C-H bond immediately are used to make a double bond towards the partial positive charge.
In the products we see the major product and water, as expected. Even though you have an intermediate, remember that an E2 mechanism technically happens in one step after -OH protonation.
Answer:
c = 0.13 j/ g.°C
Explanation:
Given data:
Mass of mercury = 29.5 g
Initial temperature = 32°C
Final temperature = 161°C
Heat absorbed = 499.2 j
Solution:
Formula:
Q = m.c. ΔT
Q = amount of heat absorbed or released
m = mass of given substance
c = specific heat capacity of substance
ΔT = change in temperature
Q = m.c. ΔT
ΔT = T2 - T1
ΔT = 161°C - 32°C
ΔT = 129 °C
Q = m.c. ΔT
c = Q / m. ΔT
c = 499.2 j / 29.5 g. 129 °C
c = 499.2 j / 3805.5 g. °C
c = 0.13 j/ g.°C
The m/z and relative abundance of the ions contributed to the peak at 21.876 min. The relative abundance will be 21.876%.
<h3>
What is relative abundance?</h3>
- The proportion of atoms with a particular atomic mass present in an element sample taken from a naturally occurring sample is known as the relative abundance of an isotope.
- When the relative abundances of an element's isotopes are multiplied by their atomic masses and the results are added up, the result is the element's average atomic mass, which is a weighted average.
- Chemists often divide the number of atoms in a particular isotope by the sum of the atoms in all the isotopes of that element, then multiply the result by 100 to determine the percent abundance of each isotope in a sample of that element.
To learn more about relative abundance with the given link
brainly.com/question/1594226
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