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The standard reduction potentials of the following half-reactions are given in Appendix E in the textbook:

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Answer:

For 1: The largest positive cell potential is of cell having 1st and 4th half reactions.

For 2: The standard electrode potential of the cell is 1.539 V

For 3: The smallest positive cell potential is of cell having 3rd and 4th half reactions. The standard electrode potential of the cell is 0.46 V

Explanation:

The substance having highest positive $E^o$ potential will always get reduced and will undergo reduction reaction.

We are given:

$Ag^++(aq.)+e^-\rightarrow Ag(s);E^o_{Ag^+/Ag}=0.799V\\\\Cu^{2+}+(aq.)+2e^-\rightarrow Cu(s);E^o_{Cu^{2+}/Cu}=0.337V\\\\Ni^{2+}(aq.)+2e^-\rightarrow Ni(s);E^o_{Ni^{2+}/Ni}=-0.28V\\\\Cr^{3+}(aq.)+3e^-\rightarrow Cr(s);E^o_{Cr^{3+}/Cr}=-0.74V$

Substance getting oxidized always act as anode and the one getting reduced always act as cathode.

To calculate the $E^o_{cell}$ of the reaction, we use the equation:

$E^o_{cell}=E^o_{cathode}-E^o_{anode}$

Cell having 1st and 2nd half reactions:

Silver has higher electrode potential. So, this will undergo reduction reaction and act as anode. Copper will undergo oxidation reaction and act as cathode.

$E^o_{cell}=0.799-0.337=0.462V$

Cell having 1st and 3rd half reactions:

Silver has higher electrode potential. So, this will undergo reduction reaction and act as anode. Nickel will undergo oxidation reaction and act as cathode.

$E^o_{cell}=0.799-(-0.28)=1.079V$

Cell having 1st and 4th half reactions:

Silver has higher electrode potential. So, this will undergo reduction reaction and act as anode. Chromium will undergo oxidation reaction and act as cathode.

$E^o_{cell}=0.799-(-0.74)=1.539V$

Cell having 2nd and 3rd half reactions:

Copper has higher electrode potential. So, this will undergo reduction reaction and act as anode. Nickel will undergo oxidation reaction and act as cathode.

$E^o_{cell}=0.337-(-0.28)=0.617V$

Cell having 3rd and 4th half reactions:

Nickel has higher electrode potential. So, this will undergo reduction reaction and act as anode. Chromium will undergo oxidation reaction and act as cathode.

$E^o_{cell}=-0.28-(-0.74)=0.46V$

Hence,

For 1: The largest positive cell potential is of cell having 1st and 4th half reactions.

For 2: The standard electrode potential of the cell is 1.539 V

For 3: The smallest positive cell potential is of cell having 3rd and 4th half reactions. The standard electrode potential of the cell is 0.46 V

8 0

3 years ago

What is the product when magnesium reacts with nitrogen? Mg(s) + N2(g) → Mg2N3(s) Mg3N(s) Mg3N2(s) MgN3(s)

bixtya [17]

Look at the periodic table to find the charge on atoms.
Magnesium is +2 and Nitrogen is -3. Since there are two nitrogen charge 2*-3 = -6 there needs to be 3 Mg then (3*2+ = 6+) to pair with the two nitrogen.
3 Mg(+2) + 2 N(-3) = Mg3N2

6 0

3 years ago

Read 2 more answers

The majority of the mass of the atom is located in the _______. A) nucleus B) core electrons C) pions and quarks D) valence elec

NeX [460]

The majority of the mass of the atom is located in the nucleus. Remember that the nucleus contains both protons and neutrons and therefore, most of the mass of the atom.

5 0

3 years ago

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A sample of Neon is in a sealed container held under isothermic conditions. The initial pressure and volume are 2.7 atm and 4.5

Marina CMI [18]

Answer:

The final volume in mL is 7.14 mL or 7.1 mL.

Explanation:

1.Use Boyle's Law( $P_{1} V_{1}= P_{2} V_{2}$ ). Re-arrange to solve for $V_{2}$ for the final volume.