If you have to write the chemical formula of a simple, binary ionic compound given the name of the compound, you follow a set of three steps. Let's go through them using magnesium chloride as an example. Write the symbols for the cation and the anion: Mg and Cl. Determine the charge on the cation and anion.
The total pressure when the new equilibrium is stabilized is half of the initial pressure of the system.
The given chemical reaction at a stable equilibrium is,
2H₂O(g)+O₂(g) = 2H₂O₂(g)
According to the ideal gas equation,
PV = nRT
P is pressure,
V is volume,
n is moles
R is gas constant,
T is temperature.
Assuming the temperature is constant.
If the volume of the system is twice the initial volume then the total pressure at the new equilibrium can be found out as,
P₁V₁ = P₂V₂
Where, P₁ and V₁ are initial volume and pressure while P₂ and V₂ are final pressure and volume.
If V₂ = 2V₁,
P₂ = P₁/2
So, the final total pressure will be half of the initial pressure.
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Answer:
[Ag⁺] = 5.0x10⁻¹⁴M
Explanation:
The product solubility constant, Ksp, of the insoluble salts PbI₂ and AgI is defined as follows:
Ksp(PbI₂) = [Pb²⁺] [I⁻]² = 1.4x10⁻⁸
Ksp(AgI) = [Ag⁺] [I⁻] = 8.3x10⁻¹⁷
The PbI₂ <em>just begin to precipitate when the product [Pb²⁺] [I⁻]² = 1.4x10⁻⁸</em>
<em />
As the initial [Pb²⁺] = 0.0050M:
[Pb²⁺] [I⁻]² = 1.4x10⁻⁸
[0.0050] [I⁻]² = 1.4x10⁻⁸
[I⁻]² = 1.4x10⁻⁸ / 0.0050
[I⁻]² = 2.8x10⁻⁶
<h3>[I⁻] = 1.67x10⁻³</h3><h3 />
So, as the [I⁻] concentration is also in the expression of Ksp of AgI and you know concentration in solution of I⁻ = 1.67x10⁻³M:
[Ag⁺] [I⁻] = 8.3x10⁻¹⁷
[Ag⁺] [1.67x10⁻³] = 8.3x10⁻¹⁷
<h3>[Ag⁺] = 5.0x10⁻¹⁴M</h3>
Weather... weather is the obvious answer
