How many molecules are there in 10 grams of N2I6?
1 answer:
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Answer:The product formed on reaction with hydroxide ion as nucleophile is 2R-hexane-2-ol.
The product formed on reaction with water would be a 50:50 mixture of
2S-hexane-2-ol. and 2R-hexane-2-ol.
Explanation:
2S-iodohexane on reactiong with hydroxide ion would undergo SN² substitution reaction that is substitution bimolecular. Hydroxide ion has a negative charge and hence it is a quite good nucleophile .
The rate of a SN² reaction depends on both the substrate and nucleophile . Here the substrate is a secondary carbon center having Iodine as a leaving group.SN² reaction takes place here as hydroxide ion is a good nucleophile and it can attack the secondary carbon center from the back side leading to the formation of 2R-hexane-2-ol.
In a SN² reaction since the the nucleophile attacks from the back-side so the product formation takes place with the inversion of configuration.
When the same substrate S-2-iodohexane undergoes a substitution reaction with water as a nucleophile then the reaction occurs through (SN¹) substitution nucleophilic unimolecular mechanism .
The rate of a SN¹ reaction depends only on the nature of substrate and is independent of the nature of nucleophile.
The SN¹ reaction is a 2 step reaction , in the first step leaving group leaves leading to the formation of a carbocation and once the carbocation is formed then any weaker nucleophile or even solvent molecules can attack leading the formation of products.
In this case a secondary carbocation would be generated in the first step and then water will attack this carbocation to form the product in the second step.
The product formed on using water as a nucleophile would be a racemic mixture of R and S isomers of hexane -2-ol in 50:50 ratio. The two products formed would be 2R-hexane-2-ol and 2S-hexane-2-ol.
Kindly refer the attachment for reaction mechanism and structure of products.
Answer:
0.329 g
Explanation:
In the context of this problem, we have a chemical reaction between hydrochloric acid and calcium hydroxide. HCl is the acid here and calcium hydroxide is the base. Hence, we have an acid-base reaction, also known as neutralization reaction.
In a neutralization reaction, water is produced as a product, as well as a salt that we obtain after we exchange the cations: calcium bonds to chloride and hydrogen bonds to hydroxide (the latter is the formation of water). This means we also produce calcium chloride as a product. The overall reaction represents this as:
Firslt of all, we wish to find the number of moles of HCl present. Having molarity and volume, this is done by applying the molarity formula. It states that molarity is equal to the rate between moles and volume:
Rearranging for moles of HCl, n:
Based on stoichiometry of the balanced chemical equation, notice that 1 mole of calcium hydroxide reacts with 2 moles of HCl, meaning:
Now that we have the expression for moles, we may also express moles of calcium hydroxide as the ratio between its mass and molar mass:
Using the last two equations, we see that:
Substitute the given data, as well as the molar mass of calcium hydroxide: