Lowery-Bronsted theory is applied here. Acc. to this theory Base accepts protons and Acids donate proton.
Part 1:
Aniline is less basic than ethylamine because the lone pair on nitrogen (which accepts proton) is not localized. It resonates throughout the conjugated system of phenyl ring. Hence due to unavailability of electrons for accepting proton it is less basic compare to ethylamine. In ethyl amine the lone pair of electron is localized and available to abstract proton.
Part 2:
In this case the alkyl groups attached to -NH₂ (in ethylamine) and -O⁻ (in ethoxide are same (i.e. CH₃-CH₂-). Ethoxide is more basic than ethylamine because ethoxide is a conjugate base of ethanol (pKa value of ethanol = 15.9 very weak acid) and the conjugate base of weak acid is always a strong base. Secondly, the oxygen atom more Electronegative than Nitrogen atom can attract more electron cloud from alkyl group as compared to Nitrogen in ethylamine. Hence, oxygen in ethoxide attains greater electron cloud than the nitrogen in ethylamine. Therefore, it is more basic than ethylamine.
Sublimation. Sublimation is the change of a solid direct to gas or vapour without becoming liquid
The given sentence is part of a longer question.
I found this question with the same sentence. So, I will help you using this question:
For the reaction N2O4<span>(g) ⇄ 2NO</span>2(g), a reaction mixture at a certain temperature initially contains both N2O4 and NO2 in their standard states (meaning they are gases with a pressure of 1 atm<span>). If </span>Kp = 0.15, which statement is true of the reaction mixture before
any reaction occurs?
(a) Q = K<span>; The reaction </span>is at equilibrium.
(b) Q < K<span>;
The reaction </span>will proceed to
the right.
(c) Q > K<span>; The reaction </span>will proceed to the left.
The answer is the option (c) Q > K<span>; The reaction will proceed to the </span>left,
since Qp<span> = </span>1<span>, and 1 > 0.15.</span>
Explanation:
Kp is the equilibrium constant in term of the partial pressures of the gases.
Q is the reaction quotient. It is a measure of the progress of a chemical reaction.
The reaction quotient has the same form of the equilibrium constant but using the concentrations or partial pressures at any moment.
At equilibrium both Kp and Q are equal. Q = Kp
If Q < Kp then the reaction will go to the right (forward reaction) trying to reach the equilibrium,
If Q > Kp then the reaction will go to the left (reverse reaction) trying to reach the equilibrium.
Here, the state is that both pressures are 1 atm, so Q = (1)^2 / 1 = 1.
Since, Q = 1 and Kp = 0.15, Q > Kp and the reaction will proceed to the left.
Answer:
I'm not a genius but it's an invisible force that pulld object towards eachother, Earth's gravity is what keeps you on the ground and what makes things fall, Anything with mass also has gravity, objects with more mass means they have more gravity
C3H8+3O2--->3CO2+8H
Therefore for every 1:3 there are 3 Carbon dioxides that form. That means find the limiting reactant from the two reactants.
5.5g(1mole C3H8/44.03g of C3H8)=0.1249 moled of C3H8 and if for every one C3H8 we can form three CO2. We can assume 0.3747 miles of CO2 will be produced.
15g of O2(1 mole O2/32g of O2)=0.4685moles O2 and if for every three O2 we can produce three CO2 we may assume a 1:1 ratio.
This means C3H8 will be your limiting reactant. Therefore 0.3747 moles of CO2 will be produced.
0.3747 moles of CO2(48.01 g of CO2/1 mole of CO2)= 17.99 grams of CO2