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Debora [2.8K]
2 years ago
7

Write an equilibrium expression for each chemical equation involving one or more solid or liquid reactants or products.

Chemistry
1 answer:
Alex_Xolod [135]2 years ago
5 0

Answer:

a.

Keq=\frac{[HCO_3^-][OH^-]}{[CO_3^{2-}]}

b.

Keq=[O_2]^3

c.

Keq=\frac{[H_3O^+][F^-]}{[HF]}

d.

Keq=\frac{[NH_4^+][OH^-]}{[NH_3]}

Explanation:

Hello there!

In this case, for the attached reactions, it turns out possible for us to write the equilibrium expressions by knowing any liquid or solid would be not-included in the equilibrium expression as shown below, with the general form products/reactants:

a.

Keq=\frac{[HCO_3^-][OH^-]}{[CO_3^{2-}]}

b.

Keq=[O_2]^3

c.

Keq=\frac{[H_3O^+][F^-]}{[HF]}

d.

Keq=\frac{[NH_4^+][OH^-]}{[NH_3]}

Regards!

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The complete question is as follows: 171 g of sucrose ( MW of 342, melting point 186 oC, boiling point very high, and vapor pressure is negligible) is dissolved in one liter of water at 25 oC. At 25 oC the vapor pressure of water is 24 mmHg. Which value is closest to the vapor pressure (VP) of this solution at 25 oC?

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Explanation:

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As moles is the mass of substance divided by its molar mass. Hence, moles of water (molar mass = 18.02 g) is calculated as follows.

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Mole fraction of water is as follows.

Mole fraction = \frac{moles of water}{total moles}\\= \frac{55.49}{55.99}\\= 0.99

Formula used to calculate vapor pressure of the solution is as follows.

P_{i} = P^{o}_{i} \times \chi_{i}

where,

P_{i} = vapor pressure of component i over the solution

P^{o}_{i} = vapor pressure of pure component i

\chi_{i} = mole fraction of i

Substitute the values into above formula to calculate vapor pressure of water as follows.

P_{i} = P^{o}_{i} \times \chi_{i}\\= 24 mm Hg \times 0.99\\= 23.76 \\or 24 mm Hg\\

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