Pyruvate is the end product of glycolysis. Its further metabolism depends on the organism and on the presence or absence of oxyg
en. Draw the structure of the product from each reaction as it would exist at pH 7. Include the appropriate hydrogen atoms. Reaction A: aerobic conditions in humans or yeast
1 answer:
The given question is incomplete. The image present in the question for Reaction A is attached below along with the answer.
Explanation:
Pyruvate molecule reacts with Coenzyme A in the presence of oxygen and it results in the formation of acetyl Coenzyme A and carbon dioxide.
The enzyme pyruvae dehydrogenase helps in catalyzing this reaction. As in this biochemical reaction gets converted into NADH.
This reaction is shown in the image attached below.
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Explanation:
Principle Quantum Numbers : It describes the size of the orbital and the energy level. It is represented by n. Where, n = 1,2,3,4....
Azimuthal Quantum Number : It describes the shape of the orbital. It is represented as 'l'. The value of l ranges from 0 to (n-1). For l = 0,1,2,3... the orbitals are s, p, d, f...
s = 1 orbital
p = 3 orbitals
d = 5 orbitals
f = 7 orbitals
For n = 4
l = 0 to (n-1) = 0 to 3 = (4s , 4p , 4d , 4f)
Number of subshells = 4
Number of orbitals = 1 + 3 + 5 + 7 = 16
The maximum number of electrons the n = 4 shell can contain:
Each orbital can holds upto two electrons, then 16 orbitals will have :
32 is the maximum number of electrons the n = 4 shell can contain
Answer:
The product is cyclohexanol
Explanation:
Firstly,
A ketone undergo a borohydride reduction reaction to form an alcohol as below,
R-CO-R' ⇒ R-CO(OH)-R'
- IR Spectrum confirms that alcohol group is existed with the peak at 3400 cm⁻¹
- From 1H-NMR, the product has 10 hydrogen atoms, the MS suggest that the formula is C₅H₁₀O (M = 86). With this formula, the alcohol is monosaturated. Since, the substance already underwent reduction reaction, the only way to suggest a monosaturated compound is a cyclic alcohol. So the compound is cyclopentanol.
- Check with other spectroscopic properties,
- 3 signals of 13C NMR confirms the structure is symmetrical, δ 24.2, (-<u>C</u>H₂-CH₂-CH(CH₂-)-OH), δ 35.5 (-CH₂-<u>C</u>H₂-CH(CH₂-)-OH), δ 73.3 (-CH₂-CH₂-<u>C</u>H(CH₂-)-OH).
- 1H NMR confirms,
1.56 δ (4H, triplet) - (-C<u>H</u>₂-CH₂-CH-OH) ; triplet as coupling with 2 H,
1.78 δ (4H, multiplet) - (-CH₂-C<u>H</u>₂-CH-OH); multiplet as coupling with 2H of CH₂, 1 H of CH
3.24 δ (1H, quintet); - (-CH₂-CH₂-C<u>H</u>(CH₂-)-OH), coupling with4 H of 2 group of CH₂
3.58 δ (1H, singlet); - (-CH₂-CH₂-CH(CH₂-)-O<u>H</u>), hydrogen of alcohol group, not tend to coupling with other hydrogen
