This is your answer:
-13 degrees C
A physical change is when something don't permanently change
"The boron-nitrogen interaction in the studied molecules shows some similarities with the N→B bond in the H3N-BH3 molecule, formally understood as covalent-dative. ... The results show that all the studied BN bonds are triple, since three two-center orbitals have been obtained."
"Formation of a dative bond or coordinate bond between ammonia and boron trifluoride. When the nitrogen donates a pair of electrons to share with the boron, the boron gains an octet. ... In addition, a pair of non-bonding electrons becomes bonding; they are delocalized over two atoms and become lower in energy."
Because size of an atom INCREASES from top to bottom and DECREASES from left to right on the periodic table. If to elements are in the same period they can't increase in size based on the up or down trend. Instead, notice that Alkali Metals are LEFT of Alkaline Earth Metals. Therefore, the Alkali Metal will be larger than the Alkaline Earth Metals.
Answer:
75 kJ/mol
Explanation:
The reactions occur at a rate, which means that the concentration of the reagents decays at a time. The rate law is a function of the concentrations and of the rate constant (k) which depends on the temperature of the reaction.
The activation energy (Ea) is the minimum energy that the reagents must have so the reaction will happen. The rate constant is related to the activation energy by the Arrhenius equation:
ln(k) = ln(A) -Ea/RT
Where A is a constant of the reaction, which doesn't depend on the temperature, R is the gas constant (8.314 J/mol.K), and T is the temperature. So, for two different temperatures, if we make the difference between the two equations:
ln(k1) - ln(k2) = ln(A) - Ea/RT1 - ln(A) + Ea/RT2
ln (k1/k2) = (Ea/R)*(1/T2 - 1/T1)
k1 = 8.3x10⁸, T1 = 142.0°C = 415 K
k2 = 6.9x10⁶, T2 = 67.0°C = 340 K
ln(8.3x10⁸/6.9x10⁶) = (Ea/8.314)*(1/340 - 1/415)
4.8 = 6.39x10⁻⁵Ea
Ea = 75078 J/mol
Ea = 75 kJ/mol
