Answer:
pKa of the histidine = 9.67
Explanation:
The relation between standard Gibbs energy and equilibrium constant is shown below as:
![\Delta{G^0} =-RT \ln \frac{[His]}{[His+]}](https://tex.z-dn.net/?f=%5CDelta%7BG%5E0%7D%20%3D-RT%20%5Cln%20%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
R is Gas constant having value = 0.008314 kJ / K mol
Given temperature, T = 293 K
Given, 
So, Applying in the equation as:-
![15\ kJ/mol=-0.008314\ kJ/Kmol\times 293\ K\times \ln \frac{[His]}{[His+]}](https://tex.z-dn.net/?f=15%5C%20kJ%2Fmol%3D-0.008314%5C%20kJ%2FKmol%5Ctimes%20293%5C%20K%5Ctimes%20%5Cln%20%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Thus,
![\frac{[His]}{[His+]}=e^{\frac{15}{-0.008314\times 293}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3De%5E%7B%5Cfrac%7B15%7D%7B-0.008314%5Ctimes%20293%7D)
![\frac{[His]}{[His+]}=0.00211](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3D0.00211)
Also, considering:-
![pH=pKa+log\frac{[His]}{[His+]}](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Given that:- pH = 7.0
So, 
<u>pKa of the histidine = 9.67</u>
The combustion reaction is as expressed,
CxHy + O2 --> CO2 + H2O
The mass fraction of carbon in CO2 is 3/11. Hence,
mass of C in CO2 = (3.14 g)(3/11) = 0.86 g C.
Given that we have 1 g of the hydrocarbon, the mass of H is equal to 0.14 g.
moles of C = 0.86 g C / 12 g = 0.0713
moles of H = 0.14 g H / 1 g = 0.14
The empirical formula for the hydrocarbon is therefore, CH₂.
Answer:
Henry Moseley
Explanation:
Dmitry Mendeleef and Lothar Meyer proposed a periodic table based on the atomic mass.
They stated a periodic law expressed as "chemical properties of elements are a periodic function of their atomic weights".
But, Henry Moseley in 1900s re-stated periodic law by changing the basis of the law from atomic weight to atomic number.
The present periodic law is stated as "the properties of elements are a periodic function of their atomic number".
If an organism is heterozygous, it has one copy of two different alleles. If an organism is homozygous, it has two copies of the same allele.
