In the herbicide linuron whose structure is shown in the image attached, there are four pi bonds.
A pi bond is formed by a sideways overlap of atomic orbitals. A sigma bond is formed by an end to end or head to head overlap of atomic orbitals. Pi bonds lead to the occurrence of multiple bonds in the molecule.
In the herbicide linuron whose structure is shown in the image attached to this answer, there are four pi bonds which are easily spotted as double bonds in the structure.
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Here we have to draw the four isomers of the compound 3-bromo-4-fluorohexane.
The four isomers of the compound is shown in the figure.
In an organic molecule the chiral -C center is that where four (4) different groups are present. In 3-bromo-4-fluorohexane the 3 and 4 positions are chiral centers. The possible isomers of a molecule can be obtained from the formula 2n. As here 2 chiral centers are present thus number of stereoisomers will be 2×2 = 4.
The four different isomers as shown in the figure are 3R-, 4R-; 3S-, 4S; 3R, 4S and 3S-, 4R- 3-bromo-4-fluorohexane.
In the 3-bromo-4-fluorohexane the functional groups are -Br, C₂H₅, -C₃H₆F and -H for 3-position and -F, -C₂H₅, -C₃H₆ and -H for 4-position respectively.
The priority of the -3 position will be Br > C₃H₆F > C₂H₅ > H and for -4 position F > C₃H₆Br > C₂H₅ > H. If the rotation from the higher priority group to lower is clockwise and anticlockwise then the S- and R- notation are used respectively. However if the -H atom is present at the horizontal position then the notation will be reverse.
Thus the four isomers of the compound is shown.
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Answer:
Lithium selenide Lithium selenide (Li2Se) 12136-60-6 Dilithium selenide lithium selenidolithium
Molecular Weight 92.9 g/mol
Dates Modify 2020-11-15 Create 2005-08-08
