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Igoryamba
3 years ago
6

Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction e

nthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.

Chemistry
1 answer:
Verdich [7]3 years ago
3 0

Answer:

Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option observations conclusions reaction ΔΗ is (pick one) The reverse of this reaction is always spontaneous. A As is (pick one) This reaction is spontaneous except below ΔΗ is (pick one) 38. °C but proceeds at a faster rate above (pick one) 91. °C As is ΔΗ iS (pick one) Crystallization of a pure compound is C spontaneous only below 146. °C. AS is (pick one) X

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3 years ago
Suppose the half-life is 9.0 s for a first order reaction and the reactant concentration is 0.0741 M 50.7 s after the reaction s
bazaltina [42]

<u>Answer:</u> The time taken by the reaction is 84.5 seconds

<u>Explanation:</u>

The equation used to calculate half life for first order kinetics:

k=\frac{0.693}{t_{1/2}}

where,

t_{1/2} = half-life of the reaction = 9.0 s

k = rate constant = ?

Putting values in above equation, we get:

k=\frac{0.693}{9}=0.077s^{-1}

Rate law expression for first order kinetics is given by the equation:

k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}     ......(1)

where,

k = rate constant  = 0.077s^{-1}

t = time taken for decay process = 50.7 sec

[A_o] = initial amount of the reactant = ?

[A] = amount left after decay process =  0.0741 M

Putting values in equation 1, we get:

0.077=\frac{2.303}{50.7}\log\frac{[A_o]}{0.0741}

[A_o]=3.67M

Now, calculating the time taken by using equation 1:

[A]=0.0055M

k=0.077s^{-1}

[A_o]=3.67M

Putting values in equation 1, we get:

0.077=\frac{2.303}{t}\log\frac{3.67}{0.0055}\\\\t=84.5s

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6 0
3 years ago
Given the following heats of combustion. CH3OH(l) + 3/2 O2(g) CO2(g) + 2 H2O(l) ΔH°rxn = -726.4 kJ C(graphite) + O2(g) CO2(g) ΔH
sergeinik [125]

Answer:

The standard enthalpy of formation of methanol is, -238.7 kJ/mole

Explanation:

The formation reaction of CH_3OH will be,

C(s)+2H_2(g)+\frac{1}{2}O_2\rightarrow CH_3OH(g),\Delta H_{formation}=?

The intermediate balanced chemical reaction will be,

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CH_3OH(g)+\frac{3}{2}O_2(g)\rightarrow CO_2(g)+2H_2O(l) , \Delta H_3=-726.4kJ/mole..[3]

Now we will reverse the reaction 3, multiply reaction 2 by 2  then adding all the equations, Using Hess's law:

We get :

C(graphite)+O_2(g)\rightarrow CO_2(g) , \Delta H_1=-393.5kJ/mole..[1]

2H_2(g)+2O_2(g)\rightarrow 2H_2O(l) ,\Delta H_2=2\times (-285.8kJ/mole)=-571.6kJ/mol..[2]

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The expression for enthalpy of formation of C_2H_4 will be,

\Delta H_{formation}=\Delta H_1+2\times \Delta H_2+\Delta H_3

\Delta H=(-393.5kJ/mole)+(-571.6kJ/mole)+(726.4kJ/mole)

\Delta H=-238.7kJ/mole

The standard enthalpy of formation of methanol is, -238.7 kJ/mole

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