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timama [110]
3 years ago
13

13.What volume of hydrogen gas is produced when 92.4 g of sodium reacts completely according to the following reaction at 25 °C

and 1 atm?
sodium (s) + water(l)------->sodium hydroxide (aq) + hydrogen(g)
Chemistry
1 answer:
Anastaziya [24]3 years ago
5 0

Answer:

44.8L of hydrogen gas

Explanation:

The reaction expression is given as:

            2Na   +  2H₂O   →    2NaOH    +  H₂

Given parameters:

Mass of sodium  = 92.4g

Unknown:

Volume of hydrogen gas  =  ?

Solution:

To solve this problem:

            1 mole of a substance at STP occupies a volume of  22.4L

Let us find the number of moles of the hydrogen gas;

 Number of moles of Na = \frac{mass}{molar mass}  

      Molar mass of Na = 23g/mol

 Number of moles  = \frac{92.4}{23}    = 4.02mole

From the balanced reaction expression:

       2 mole of Na will produce 1 mole of hydrogen gas

     4.02 mole of Na will produce \frac{4.02}{2}   = 2mole of hydrogen gas

So

         1 mole of a substance at STP occupies a volume of  22.4L

        2 mole of hydrogen gas will occupy a volume of 2 x 22.4  = 44.8L of hydrogen gas

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Explanation:

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H_3PO_4(aq.)+3LiOH(aq.)\rightarrow Li_3PO_4(aq.)+3H_2O(l)

H_3PO_4 is a weak acid and hence will not dissociate into ions whereas LiOH is a strong base and will easily dissociate into ions.

The product Li_3PO_4 is soluble in water and hence, will dissociate into its respective ions. Hence, the ionic equation for this reaction is:

H_3PO_4(aq.)+3Li^{3+}(aq.)+3OH^-(aq.)\rightarrow 3Li^{3+}(aq.)+PO_4^{3-}(aq.)+3H_2O(l)

Net ionic equation becomes:

H_3PO_4(aq.)+3OH^-(aq.)\rightarrow PO_4^{3-}(aq.)+3H_2O(l)

So, the correct option is 1.

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2HBr(aq.)+Co(OH)_2(aq.)\rightarrow CoBr_2(aq.)+2H_2O(l)

HBr and Co(OH)_2 are strong acid and strong base respectively, hence they will easily dissociate into ions.

The product, CoBr_2 is is soluble in water and hence, will dissociate into its respective ions. Hence, the ionic equation for this reaction is:

2H^+(aq.)+2Br^-(aq.)+Co^{2+}(aq.)+2OH^-(aq.)\rightarrow Co^{2+}(aq.)+2Br^-(aq.)+H_2O(l)

The net ionic equation becomes:

H^+(aq.)+OH^-(aq.)\rightarrow H_2O(l)

So, the correct option is 3.

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3) A water molecule now abstracts a proton from the carbon adjacent to the carbocation leading to the formation of cyclohexene and the regeneration of the acid catalyst. This is an E1 mechanism because it proceeds via a carbocation intermediate and not a concerted transition state, hence the answer.

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