Apsidal precession—The major axis of Moon's elliptical orbit rotates by one complete revolution once every 8.85 years in the same direction as the Moon's rotation itself.
Answer:
True
Explanation:
The gaseous state is characterized in that the cohesion forces are usually null, in which the particles have their maximum mobility. The particles tend to occupy all the available volume, so their shape and volume are variable. The gaseous state is a dispersed state of matter, which means that the molecules are separated by distances much larger than the diameter of the gas molecules.
With what are you need help?
Volume is the thing
…………….
(a)
pH = 4.77
; (b)
[
H
3
O
+
]
=
1.00
×
10
-4
l
mol/dm
3
; (c)
[
A
-
]
=
0.16 mol⋅dm
-3
Explanation:
(a) pH of aspirin solution
Let's write the chemical equation as
m
m
m
m
m
m
m
m
l
HA
m
+
m
H
2
O
⇌
H
3
O
+
m
+
m
l
A
-
I/mol⋅dm
-3
:
m
m
0.05
m
m
m
m
m
m
m
m
l
0
m
m
m
m
m
l
l
0
C/mol⋅dm
-3
:
m
m
l
-
x
m
m
m
m
m
m
m
m
+
x
m
l
m
m
m
l
+
x
E/mol⋅dm
-3
:
m
0.05 -
l
x
m
m
m
m
m
m
m
l
x
m
m
x
m
m
m
x
K
a
=
[
H
3
O
+
]
[
A
-
]
[
HA
]
=
x
2
0.05 -
l
x
=
3.27
×
10
-4
Check for negligibility
0.05
3.27
×
10
-4
=
153
<
400
∴
x
is not less than 5 % of the initial concentration of
[
HA
]
.
We cannot ignore it in comparison with 0.05, so we must solve a quadratic.
Then
x
2
0.05
−
x
=
3.27
×
10
-4
x
2
=
3.27
×
10
-4
(
0.05
−
x
)
=
1.635
×
10
-5
−
3.27
×
10
-4
x
x
2
+
3.27
×
10
-4
x
−
1.635
×
10
-5
=
0
x
=
1.68
×
10
-5
[
H
3
O
+
]
=
x
l
mol/L
=
1.68
×
10
-5
l
mol/L
pH
=
-log
[
H
3
O
+
]
=
-log
(
1.68
×
10
-5
)
=
4.77
(b)
[
H
3
O
+
]
at pH 4
[
H
3
O
+
]
=
10
-pH
l
mol/L
=
1.00
×
10
-4
l
mol/L
(c) Concentration of
A
-
in the buffer
We can now use the Henderson-Hasselbalch equation to calculate the
[
A
-
]
.
pH
=
p
K
a
+
log
(
[
A
-
]
[
HA
]
)
4.00
=
−
log
(
3.27
×
10
-4
)
+
log
(
[
A
-
]
0.05
)
=
3.49
+
log
(
[
A
-
]
0.05
)
log
(
[
A
-
]
0.05
)
=
4.00 - 3.49
=
0.51
[
A
-
]
0.05
=
10
0.51
=
3.24
[
A
-
]
=
0.05
×
3.24
=
0.16
The concentration of
A
-
in the buffer is 0.16 mol/L.
hope this helps :)
