Answer:
The molarity of the HCl solution should be 4.04 M
Explanation:
<u>Step 1:</u> Data given
volume of HCl solution = 10.00 mL = 0.01 L
volume of a 1.6 M NaOH solution = 25.24 mL = 0.02524 L
<u>Step 2:</u> The balanced equation
HCl + NaOH → NaCL + H2O
Step 3: Calculate molarity of HCl
n1*C1*V1 = n2*C2*V2
Since the mole ratio for HCl and NaOH is 1:1 we can just write:
C1*V1 =C2*V2
⇒ with C1 : the molarity of HCl = TO BE DETERMINED
⇒ with V1 = the volume og HCl = 10 mL = 0.01 L
⇒ with C2 = The molarity of NaOH = 1.6 M
⇒ with V2 = volume of NaOH = 25.24 mL = 0.02524 L
C1 * 0.01 = 1.6 * 0.02524
C1 = (1.6*0.02524)/0.01
C1 = 4.04M
The molarity of the HCl solution should be 4.04 M
Answer:
volume of the container will decreases if pressure increases.
Explanation:
According to Boyle's law:
Pressure is inversely proportional to volume which means if pressure of a gas increases the volume of the gas will decreases as gas molecules will collide and come closer forcefully so volume will decreases. And its formula for determining volume and pressure is:
<em>PV=nRT</em>
where "R" is a ideal gas constant
"T" is temperature and
"n" is number of particles given in moles while "V" is volume and "P" is pressure.
<u>Answer:</u> The standard free energy change of formation of 
is 92.094 kJ/mol
<u>Explanation:</u>
We are given:
Relation between standard Gibbs free energy and equilibrium constant follows:
where,
= standard Gibbs free energy = ?
R = Gas constant = 
T = temperature = ![25^oC=[273+25]K=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B273%2B25%5DK%3D298K)
K = equilibrium constant or solubility product = 
Putting values in above equation, we get:
For the given chemical equation:
The equation used to calculate Gibbs free change is of a reaction is:
![\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the Gibbs free energy change of the above reaction is:
![\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag%5E%2B%28aq.%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag_2S%28s%29%29%7D%29%5D)
We are given:
Putting values in above equation, we get:
![285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol](https://tex.z-dn.net/?f=285.794%3D%5B%282%5Ctimes%2077.1%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%28-39.5%29%29%5D%5C%5C%5C%5C%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%3D92.094J%2Fmol)
Hence, the standard free energy change of formation of is 92.094 kJ/mol
