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tatiyna
3 years ago
9

5. Which choice best represents the relationship between wavelength and frequency?

Chemistry
1 answer:
Arte-miy333 [17]3 years ago
4 0
When frequency increases, wavelength increases
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3 0
4 years ago
Consider a solution formed by mixing 50.0 mL of 0.100 M H2SO4, 30.0 mL of 0.1133 M HOCl, 25.0 mL of 0.200 M NaOH, 25.0 mL of 0.1
NARA [144]

Answer:

The pH of this solution is 12.1.

Explanation:

H_2SO_4

H_2SO_4\rightarrow 2H^++SO_4^{2-}

1 mole of sulfuric acid gives 2 moles of hydrogen ions, then 0.100 M of sulfuric acid will give :

[H^+]=2\times [H_2SO_4]=2\times 0.100 M= 0.200 M

Volume of sulfuric acid solution = 50.0 mL = 0.050 L ( 1 mL = 0.001 L)

Moles of hydrogen ions in sulfuric acid solution :a

a=0.200 M\times 0.050 L=0.01 mol

HOCl

The dissociation constant value of HOCl = K_a=3.5\times 10^{-8}

HOCl\rightleftharpoons H^++OCl^-

initially

0.1133 M         0        0

At equilibrium :

(0.1133-x)         x         x

The expression of dissociation constant is given as:

K_a=\frac{[H^+][OCl^-]}{[HOCl]}

3.5\times 10^{-8}=\frac{x\times x}{(0.1133-x)}

Solving for x:

x = 6.295\times 10^{-5} M

[H^+]=6.295\times 10^{-5} M

Volume of HOCl solution = 30.0 mL = 0.030 L ( 1 mL = 0.001L)

Moles of hydrogen ions in HOCl solution = b

b=6.295\times 10^{-5} M\times 0.030 L=1.8885\times 10^{-6} mol

Total moles of hydrogen ions = a + b

=0.01 mol +1.8885\times 10^{-6} mol=0.010002 mol

NaOH

NaOH\rightarrow Na^++OH^{-}

1 mole of NaOH gives 1 mole of hydroxide ions, then 0.200 M of NaOH acid will give :

[OH^-]=1\times [NaOH]=1\times 0.200 M= 0.200 M

Volume of NaOH solution = 25.0 mL = 0.025 L ( 1 mL = 0.001 L)

Moles of hydroxide ions in NaOH solution : c

c=0.200 M\times 0.025 L=0.005 mol

Ba(OH)_2

Ba(OH)_2\rightarrow Ba^{2+}+2OH^{-}

1 mole of Ba(OH)_2 gives 2 mole of hydroxide ions, then 0.100 M of

[OH^-]=2\times [Ba(OH)_2]=1\times 0.200 M= 0.200 M

Volume of Ba(OH)_2solution = 25.0 mL = 0.025 L ( 1 mL = 0.001 L)

Moles of hydroxide ions in Ba(OH)_2 solution : d

d=0.200 M\times 0.025 L=0.005 mol

KOH

KOH\rightarrow K^++OH^{-}

1 mole of KOH gives 1 mole of hydroxide ions, then 0.170 M of KOH will give :

[OH^-]=1\times [KOH]=1\times 0.170 M= 0.170 M

Volume of KOH solution = 10.0 mL = 0.010 L ( 1 mL = 0.001 L)

Moles of hydroxide ions in KOH solution : e

e=0.170 M\times 0.010 L=0.0017 mol

Total moles of hydroxide ions : c + d + e

0.005 mol + 0.005 mol + 0.0017 mol = 0.0117 mol

Total moles of hydrogen ions = 0.010002 mol

Total moles of hydroxide ions =  0.0117 mol

1 mole of hydrogen ion reacts with 1 mole of hydroxide ion to from a water with neutral pH.

Hydrogen ions <  hydroxide ion

So, 0.0117 moles of hydroxide ion will neutralize 0.0117 moles of hydrogen ions.

Moles of hydroxide left after neutralization = 0.0117 mol - 0.010002 mol

= 0.001698 moles

Concentration of hydroxide ions left in the solution :

[OH^-]=\frac{0.001698 mol}{0.050 L+0.030 L+0.025 L+0.025 L+0.010 L}=0.01213 M

pOH=-\log[OH^-]=-\log[0.01213 M]=1.9

pH = 14 - pOH

pH = 14 - 1.9= 12.1

The pH of this solution is 12.1.

7 0
4 years ago
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