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Soloha48 [4]
3 years ago
11

When an endothermic chemical reaction (the system) occurs inside a calorimeter containing water (the surroundings) and no heat e

scapes from the calorimeter, which of the following statements is true?
a. Heat flows from the system to the surroundings and the temperature of the water increases.
b. Heat flows from the surroundings to the system and the temperature of the water decreases.
c. Heat flows from the system to the surroundings and the temperature of the water decreases.
d. Heat flows from the surroundings to the system and the temperature of the water increases.
Chemistry
1 answer:
Nostrana [21]3 years ago
8 0

Answer:

b. Heat flows from the surroundings to the system and the temperature of the water decreases.

Explanation:

The laws of thermodynamics lets us know that energy is neither created nor destroyed but can be converted from one form to another. Also, energy transfer does accompany chemical reactions in the form of heat.

For an endothermic reaction, heat is absorbed by the system from the surroundings. This leads to a drop in the temperature of the surroundings as energy is removed.

This implies that the water temperature decreases.

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In the laboratory, a general chemistry student measured the pH of a 0.486 M aqueous solution of triethanolamine, C6H15O3N to be
STatiana [176]

Answer:

Kb = 6.22x10⁻⁷

Explanation:

Triethanolamine, C₆H₁₅O₃N, is in equilibrium with water:

C₆H₁₅O₃N(aq) + H₂O(l) ⇄ C₆H₁₅O₃NH⁺(aq) + OH⁻(aq)

Kb is defined from concentrations in equilibrium, thus:

Kb = [C₆H₁₅O₃NH⁺] [OH⁻] / [C₆H₁₅O₃N]

The equilibrium concentration of these compounds could be written as:

[C₆H₁₅O₃N] = 0.486M - X

[C₆H₁₅O₃NH⁺] = X

[OH⁻] = X

pH is -log [H⁺], thus, [H⁺] = 10^-pH = 1.820x10⁻¹¹M

Also, Kw = [OH⁻] ₓ [H⁺];

1x10⁻¹⁴ = [OH⁻] ₓ [H⁺]

1x10⁻¹⁴ = [OH⁻] ₓ [1.820x10⁻¹¹M]

5.495x10⁻⁴M = [OH⁻], that means <em>X = 5.495x10⁻⁴M</em>

Replacing in Kb formula:

Kb = [5.495x10⁻⁴M] [5.495x10⁻⁴M] / [0.486M-5.495x10⁻⁴M]

<em>Kb = 6.22x10⁻⁷</em>

<em></em>

5 0
3 years ago
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