Answer:
Climate
Explanation:
The 3 pieces of evidence are fossils, rocks, and mountain ranges all are included except climate
<u>Answer:</u> The standard free energy change of formation of
is 92.094 kJ/mol
<u>Explanation:</u>
We are given:

Relation between standard Gibbs free energy and equilibrium constant follows:

where,
= standard Gibbs free energy = ?
R = Gas constant = 
T = temperature = ![25^oC=[273+25]K=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B273%2B25%5DK%3D298K)
K = equilibrium constant or solubility product = 
Putting values in above equation, we get:

For the given chemical equation:

The equation used to calculate Gibbs free change is of a reaction is:
![\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the Gibbs free energy change of the above reaction is:
![\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag%5E%2B%28aq.%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag_2S%28s%29%29%7D%29%5D)
We are given:

Putting values in above equation, we get:
![285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol](https://tex.z-dn.net/?f=285.794%3D%5B%282%5Ctimes%2077.1%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%28-39.5%29%29%5D%5C%5C%5C%5C%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%3D92.094J%2Fmol)
Hence, the standard free energy change of formation of
is 92.094 kJ/mol
Answer: The pH at equivalence point for the given solution is 5.59.
Explanation:
At the equivalence point,

So, first we will calculate the moles of
as follows.
= 0.0845 mol
Now, volume of
present will be calculated as follows.
Volume = 
= 
= 0.1891 L
Therefore, the total volume will be the sum of the given volumes as follows.
110 ml + 189.1 ml
= 299.13 ml
or, = 0.2991 L
Now, ![[CH_{3}NH_{3}^{+}] = \frac{0.0845 mol}{0.2991 L}](https://tex.z-dn.net/?f=%5BCH_%7B3%7DNH_%7B3%7D%5E%7B%2B%7D%5D%20%3D%20%5Cfrac%7B0.0845%20mol%7D%7B0.2991%20L%7D)
= 0.283 M
Chemical equation for this reaction is as follows.

As,
= 
= 
Now, ![[HNO_{3}] = \sqrt{k_{a}[CH_{3}NH_{3}^{+}]}](https://tex.z-dn.net/?f=%5BHNO_%7B3%7D%5D%20%3D%20%5Csqrt%7Bk_%7Ba%7D%5BCH_%7B3%7DNH_%7B3%7D%5E%7B%2B%7D%5D%7D)
= 
= 
Now, pH will be calculated as follows.
pH = ![-log [H_{3}O^{+}]](https://tex.z-dn.net/?f=-log%20%5BH_%7B3%7DO%5E%7B%2B%7D%5D)
= 
= 5.59
Thus, we can conclude that pH at equivalence point for the given solution is 5.59.
Composed of molecules formed by atoms of two or more different elements.