In the structure of nylon 6,6 we have amide groups. In this functional group, We have a nitrogen bond to hydrogen, so in this bond, we will have a dipole, due to the electronegativity difference. Nitrogen has more electronegativity than hydrogen, therefore a positive dipole would be generated in the hydrogen atom. Additionally, in the carbonyl group (C=O) due to the oxygen, we will have also a dipole, in this case, a negative dipole because the oxygen atom has more electronegativity (compare with carbon).

When we put two strings of nylon 6,6 the positive dipole will interact with the negative dipole and vice-versa and we will obtain the "hydrogen bonds".

See figure 1

I hope it helps!

3 0

3 years ago

Determine the molar solubility for pb3(po4)2 in pure water. ksp for pb3(po4)2 is 1.0 x 10-54.

hoa [83]

Dissociation of Pb₃(PO₄)₂ is;
Pb₃(PO₄)₂(s) ⇆ 3Pb²⁺(aq) + 2PO₄³⁻(aq)
initial - -
change -X +3X +2X
Equilibrium 3X 2X

Ksp = [Pb²⁺(aq)]³ [PO₄³⁻(aq)]²
1.0 x 10⁻⁵⁴ = (3X)³ (2X)²
1.0 x 10⁻⁵⁴ = 108X⁵
X = 6.21 x 10⁻¹² M

Hence the molar solubility of Pb₃(PO₄)₂ is 6.21 x 10⁻¹² M.

7 0

3 years ago