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Crank
3 years ago
7

The precision of a method is being established, and the

Chemistry
1 answer:
Lemur [1.5K]3 years ago
7 0

Answer:

No,  22.09%  is not a valid measurement

Explanation:

Precision has to do with how close a given set of measured values are to each other. It is quite different from accuracy. Accuracy refers to how close a given set of values is to the true value. A given set of values may be precise but not accurate and vice versa.

If we look at the values obtained;  22.09%,  22.15%, 22.18%, 22.23%, 22.25%, the value 22.09% is too far off the other values. This implies that it does not represent a valid measurement since it is not close to all the other values obtained.

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0.10 M potassium chromate is slowly added to a solution containing 0.20 M AgNO3 and 0.20 M Ba(NO3)2. What is the Ag+ concentrati
erastova [34]

Answer:

[Ag^{+}]=4.2\times 10^{-2}M

Explanation:

Given:

[AgNO3] = 0.20 M

Ba(NO3)2 = 0.20 M

[K2CrO4] = 0.10 M

Ksp of Ag2CrO4 = 1.1 x 10^-12

Ksp of BaCrO4 = 1.1 x 10^-10

BaCrO_4 (s)\leftrightharpoons  Ba^{2+}(aq)\;+\;CrO_{4}^{2-}(aq)

Ksp=[Ba^{2+}][CrO_{4}^{2-}]

1.2\times 10^{-10}=(0.20)[CrO_{4}^{2-}]

[CrO_{4}^{2-}]=\frac{1.2\times 10^{-10}}{(0.20)}= 6.0\times 10^{-10}

Now,

Ag_{2}CrO_4(s) \leftrightharpoons  2Ag^{+}(aq)\;+\;CrO_{4}^{2-}(aq)

Ksp=[Ag^{+}]^{2}[CrO_{4}^{2-}]

1.1\times 10^{-12}=[Ag^{+}]^{2}](6.0\times 10^{-10})

[Ag^{+}]^{2}]=\frac{1.1\times 10^{-12}}{(6.0\times 10^{-10})}= 1.8\times 10^{-3}

[Ag^{+}]=\sqrt{1.8\times 10^{-3}}=4.2\times 10^{-2}M

So, BaCrO4 will start precipitating when [Ag+] is 4.2 x 1.2^-2 M

                       

7 0
3 years ago
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