Answer:
Yes
Explanation:
The tilt of the Earth means the Earth will lean towards the Sun (Summer) or lean away from the Sun (Winter) 6 months later. In between these, Spring and Autumn will occur. The North pole always points the same way as the Earth revolves around the Sun.
Answer:
a) ΔGº= -49,9 KJ/mol = - 50 KJ/mol
b) The reaction goes to the right to formation of products
c) ΔG= 84,42 KJ/mol. The direction is to reactive, to the left
Explanation:
a) ΔGº= - RTLnKf
You need to convert Cº to K. 25ºC=298K
Then, ΔGº= - 3,814 J/molK * 298K* Ln(5.6 *10^8)= - 49906 J/mol = -49,9 KJ/mol = - 50 KJ/mol
b) The ΔGº < 0, that means the direct reaction is spontaneous when te reactive and products are in standard state. In other words the reaction goes to the right, to formation of products
c) The general ecuation for chemical reaction is aA + bB → cD + dD. Thus
ΔG=ΔGº + RTLn (([C]^c*[D]^d)/[A]^a*[B]^b)
In this case,
ΔG=ΔGº + RTLn ([Ni(NH3)62+] / [Ni2+]*[NH3]^6 )= 84417 J/mol =84,42 KJ/mol
ΔG >0 means the reaction isn't spontaneous in the direction of the products. Therefore the direction is to reactive, to the left
Answer:
A reaction is non-spontaneous at any temperature when the Gibbs free energy > 0.
Explanation:
There is a state function, that determines if a reaction is sponaneous or non spontaneous:
ΔG = Gibbs free energy
A reaction is non spontaneous when it does require energy to produce that reaction. It will be spontaneous, when the reaction does not require energy to be occured.
The formula is: ΔG = ΔH - T.ΔS
ΔH → Enthalpy → Energy gained or realeased as heat.
ΔH < 0 → <em>Exothermic reaction. Spontaneity is favored
</em>
T → Temperature
ΔS → Entropy → Degree of disorder of a system.
When the system has a considered disorder ΔS > 0, disorder increases.
When the system is more ordered, ΔS < 0, disorder decreases.
The reaction will be non spontaneous if, the enthalpy is positive (endothermic reaction) and the ΔS < 0 (disorder decreases). It will not occur if we do not give energy.
ΔG < 0 → Spontaneous reaction
ΔG > 0 → Non spontaneous reaction
ΔG = 0 → System in equilibrium
