Answer:- 3. 
and 
Explanations:- An empirical formula is the simplest whole number ratio of atoms of each element present in the molecule/compound.
For example, the molecular formula of benzene is 
. The ratio of C to H in it is 6:6 that could be simplified to 1:1. So, an empirical formula of benzene is CH.
In the first pair, the ratio of C to H in first molecule is 2:4 that could be simplified to 1:2 and the empirical formula is 
. In second molecule the ratio of C to H is 6:6 and it could be simplified to 1:1. and the empirical formula is CH. Empirical formulas are different for both the molecules of first pair and so it is not the right choice.
In second pair, C to H ratio in first molecule is 1:2, so the empirical formula is . The C to H ratio for second molecule is 1:4, so the empirical formula is 
. Here also, the empirical formulas are not same and hence it is also not the right choice.
In third pair, C to H ratio in first molecule is 1:3, so the empirical formula is . In second molecule the C to H ratio is 2:6 and it is simplified to 1:3. So, the empirical formula for this one is also . Hence. this is the correct choice.
In fourth pair, first molecule empirical formula is CH. Second molecule has 2:4 that is 1:2 mole ratio of C to H and so its empirical formula is . As the empirical formulas are different, it is not the right choice.
So, the only and only correct pair is the third one. 3. and
The 38 elements in groups 3 through 12 of the periodic table are called "transition metals". As with all metals, the transition elements are both ductile and malleable, and conduct electricity and heat. The interesting thing about transition metals is that their valence electrons, or the electrons they use to combine with other elements, are present in more than one shell. This is the reason why they often exhibit several common oxidation states. There are three noteworthy elements in the transition metals family. These elements are iron, cobalt, and nickel, and they are the only elements known to produce a magnetic field I HOPE THIS HELP:)
DE = dH - PdV
<span>2 H2O(g) → 2 H2(g) + O2(g) </span>
<span>You can see that there are 2 moles of gas in the reactants and 3 moles of gas in the products. </span>
<span>1 moles of ideal gas occupies the same volume as 1 mole of any other ideal gas under the same conditions of temp and pressure. </span>
<span>Since it is done under constant temp and pressure that means the volume change will be equal to the volume of 1 mole of gas </span>
<span>2 moles reacts to form 3 moles </span>
<span>The gas equation is </span>
<span>PV = nRT </span>
<span>P = pressure </span>
<span>V = volume (unknown) </span>
<span>n = moles (1) </span>
<span>R = gas constant = 8.314 J K^-1 mol^-1 </span>
<span>- the gas constant is different for different units of temp and pressure (see wikki link) in this case temp and pressure are constant, and we want to put the result in an equation that has Joules in it, so we select 8.314 JK^-1mol^-1) </span>
<span>T = temp in Kelvin (kelvin = deg C + 273.15 </span>
<span>So T = 403.15 K </span>
<span>Now, you can see that PV is on one side of the equation, and we are looking to put PdV in our dE equation. So we can say </span>
<span>dE = dH -dnRT (because PV = nRT) </span>
<span>Also, since the gas constant is in the unit of Joules, we need to convert dH to Joules </span>
<span>dH = 483.6 kJ/mol = 483600 Joules/mol </span>
<span>dE = 483600 J/mol - (1.0 mol x 8.314 J mol^-1K-1 x 403.15 K) </span>
<span>dE = 483600 J/mol - 3351.77 J </span>
<span>dE = 480248.23 J/mol </span>
<span>dE = 480.2 kJ/mol </span>
