Answer:
Ammonia is the richest source of nitrogen on a mass percentage basis because it has 82.35% of nitrogen by mass.
Explanation:
Percentage of element in compound :

(a) Urea, 
Molar mass of urea = 60 g/mol
Atomic mass of nitrogen = 14 g/mol
Number of nitrogen atoms = 2

(b) Ammonium nitrate, 
Molar mass of ammonium nitrate = 80 g/mol
Atomic mass of nitrogen = 14 g/mol
Number of nitrogen atoms = 2

(c) Nitric oxide, NO
Molar mass of nitric oxide = 30 g/mol
Atomic mass of nitrogen = 14 g/mol
Number of nitrogen atoms = 1

(d) Ammonia, 
Molar mass of ammona = 17 g/mol
Atomic mass of nitrogen = 14 g/mol
Number of nitrogen atoms = 1
Ammonia is the richest source of nitrogen on a mass percentage basis because it has 82.35% of nitrogen by mass.
Explanation:
Relation between pressure, latent heat of fusion, and change in volume is as follows.

Also, 
where,
is the difference in specific volumes.
Hence, 
As,
= 22.0 J/mol K
And,
...... (1)
where,
= density of water
= density of ice
M = molar mass of water =
Therefore, using formula in equation (1) we will calculate the volume of fusion as follows.
=
=
Therefore, calculate the required pressure as follows.

=
or, = 145 bar/K
Hence, for change of 1 degree pressure the decrease is 145 bar and for 4.7 degree change dP =
= 681.5 bar
Thus, we can conclude that pressure should be increased by 681.5 bar to cause 4.7 degree change in melting point.