Rationalize the following statements and give chemical reactions .

Is copper ii sulphate (solution) blue or green?

slavikrds [6]

Copper II sulfate solution is blue.

8 0

3 years ago

Blue colour of cupric nitrate on strongly heating gives gives black cupric oxide powder along with oxygen gas and nitrogen dioxi

Zinaida [17]

Please see the image.

6 0

3 years ago

He chemical formula for lithium hydride is LiH A chemist determined by measurements that 0.0800 moles of lithium hydride partici

sweet-ann [11.9K]

Answer:

Mark me brainlist I will then answer in comment

3 0

3 years ago

A 3.00-kg block of copper at 23.0°C is dropped into a large vessel of liquid nitrogen at 77.3 K. How many kilograms of nitrogen

hammer [34]

Answer:

1.2584kg of nitrogen boils.

Explanation:

Consider the energy balance for the overall process. There are not heat or work fluxes to the system, so the total energy keeps the same.

For the explanation, the 1 and 2 subscripts will mean initial and final state, and C and N2 superscripts will mean copper and nitrogen respectively; also, liq and vap will mean liquid and vapor phase respectively.

The overall energy balance for the whole system is:

$U_1=U_2$

The state 1 is just composed by two phases, the solid copper and the liquid nitrogen, so: $U_1=U_1^C+U_1^{N_2}$

The state 2 is, by the other hand, composed by three phases, solid copper, liquid nitrogen and vapor nitrogen, so:

$U_2=U_2^C+U_{2,liq}^{N_2}+U_{2,vap}^{N_2}$

So, the overall energy balance is:

$U_1^C+U_1^{N_2}=U_2^C+U_{2,liq}^{N_2}+U_{2,vap}^{N_2}$

Reorganizing,

$U_1^C-U_2^C=U_{2,liq}^{N_2}+U_{2,vap}^{N_2}-U_1^{N_2}$

The left part of the equation can be written in terms of the copper Cp because for solids and liquids Cp≅Cv. The right part of the equation is written in terms of masses and specific internal energy:

$m_C*Cp*(T_1^C-T_2^C)=m_{2,liq}^{N_2}u_{2,liq}^{N_2}+m_{2,vap}^{N_2}u_{2,vap}^{N_2}-m_1^{N_2}u_1^{N_2}$

Take in mind that, for the mass balance for nitrogen, $m_1^{N_2}=m_{2,liq}^{N_2}+m_{2,vap}^{N_2}$ ,

So, let's replace $m_1^{N_2}$ in the energy balance:

$m_C*Cp*(T_1^C-T_2^C)=m_{2,liq}^{N_2}u_{2,liq}^{N_2}+m_{2,vap}^{N_2}u_{2,vap}^{N_2}-m_{2,liq}^{N_2}u_1^{N_2}-m_{2,vap}^{N_2}u_1^{N_2}$

So, as you can see, the term $m_{2,liq}^{N_2}u_{2,liq}^{N_2}$ disappear because $u_{2,liq}^{N_2}=u_{1,liq}^{N_2}$ (The specific energy in the liquid is the same because the temperature does not change).

$m_C*Cp*(T_1^C-T_2^C)=m_{2,vap}^{N_2}u_{2,vap}^{N_2}-m_{2,vap}^{N_2}u_1^{N_2}$

$m_C*Cp*(T_1^C-T_2^C)=m_{2,vap}^{N_2}(u_{2,vap}^{N_2}-u_1^{N_2})$

The difference $(u_{2,vap}^{N_2}-u_1^{N_2})$ is the latent heat of vaporization because is the specific energy difference between the vapor and the liquid phases, so:

$m_{2,vap}^{N_2}=\frac{m_C*Cp*(T_1^C-T_2^C)}{(u_{2,vap}^{N_2}-u_1^{N_2})}$

$m_{2,vap}^{N_2}=\frac{3kg*0.092\frac{cal}{gC} *(296.15K-77.3K)}{48.0\frac{cal}{g}}\\m_{2,vap}^{N_2}=1.2584kg$

3 0

3 years ago

Given that an E2 reaction proceeds with anti periplanar stereochemistry, draw the products of each elimination. The alkyl halide

serg [7]

Answer:

See explanation below

Explanation:

The first two pictures show the reagents used in these reactions a) and b). As it was stated, An E2 reaction proceeds with an antiperiplanar stereochemistry, so in the case of reaction a) it fill form a product with the groups in opposite directions. In other words, a Trans product.

In the case of reaction b) we have the same reaction, with the difference that we have changed the CH3 and phenyl group of positions. This will cause that the reaction will proceed the same but the stereochemistry of the final product will be changed too. In this case, and according to the picture 3 attached, we can see that the product formed is a cis product. So we can conclude that the relation of product a) and b) is that they are isomers, the trans and cis isomers respectively. See picture below for mechanism and products

7 0

3 years ago